環保專案成果報告查詢系統

專案計畫編號
經費年度	098
計畫經費	5,300 千元
專案開始日期	2009/11/02
專案結束日期	2010/11/01
專案主持人	陳永明
主辦單位	雲林縣環境保護局
承辦人	郭子衛
執行單位	元科科技股份有限公司
專案分類	大氣空氣
中文關鍵字	委員現場查核、質量平衡、water 9
英文關鍵字	Committee on-site examination, mass balance, water 9
協同主持人
共同主持人
計畫聯絡人	駱黔光
計畫聯絡電話	05-5374060#
計畫聯絡信箱	lc@email.green99.com.tw

中文摘要	「98年度加強離島工業區空氣污染物整合執行計畫」自98年11月2日至99年11月1日止，計12個月，已達到彙整及確認離島工業區近三年排放量前10大製程及其空氣污染物排放量、10廠次委員現場查核、質量平衡方式確認近三年來排放量前20大製程及4場次教育訓練、5場次查核進度會議、掌握儲槽之逸散性污染源排放量推估方法、完成六輕南亞麥寮廢水廠、海豐廢水廠、長春大連綜合廢水廠、合成酚、對苯二甲酸、台塑石化等廢水廠之water 9模式模擬推估及21廠油漆塗裝作業排放量推估、配合離島許可計畫陳情案件進行廠區異味採樣分析36件次等執行目標。排放量前10大製程，由近三年各種排放比對結果各種排放量皆小於許可證核發的排放量，空污費申報資料完整性及一致性尚佳，由檢測資料比對結果，97年度發電廠硫氧化物排放濃度有升高情形，經查係因受景氣影響，為減少燃料成本劣質煤使用比例增加之故；10廠次20個製程的委員現場查核結果及質能平衡，質能平衡閉合性良好，但仍存在中間產品、副原料未申報及廢氣燃燒塔操作法規符合度與實際防制效率的疑慮等問題；目前六輕儲槽之排放量推估方法，經驗證已確認是依據AP-42第五版計算，但部分儲槽經由離島VOC計畫實測結果證實仍有洩漏及實際蒸氣壓與設計蒸氣壓有差異，這將影響排放量推估結果，因此有必要加以驗證；water 9模式模擬推估廢水處理廠VOCs排放量與SCCcod計算結果比對，不如預期water 9推估結果絕對高於SCCcod計算結果，其原因為water 9推估結果主要受到廢水中VOCs物種及濃度、廢水量、處理單元規模等因素影響，因此其推估結果較SCCcod計算結果客觀，但整體推估結果仍大於SCCcod計算結果；21大廠98年油漆及調薄劑用量總計為1166噸，依據環保署96年年度排放更新引用排放係數計算結果為601噸，另依SCC排放係數及台灣區塗料油漆工業同業公會所提出的排放係數個別予以計算結果分別為898噸與700噸，若以離島工業區現行使用油漆固形物比例及調薄劑比例，建議以環保署96年年度排放更新引用排放係數計算較為合理；異味採樣分析本年度已完成31點次陳情案件，12點次污染源製程區及周界採樣分析作業，而31點次陳情案件中有26點次是本計畫負責送驗，統計陳情案件發生的風向以北到西北佔61%最多，其次為西到西南佔16%，陳情頻率最高者為新興國小19%，其次為海豐分校13%，統計陳情案件所測得31種物種中非六輕各廠申報的物種占4種，而31種物種中烷類物種占39％為最多，其次為苯類占23％。指紋資料調查周界採樣分析結果檢測出物種中，有九成幾乎於排放管道成份分析中可測得，其他為製程原料與反應生成物。另從離島工業區所提供排放管道成分析結果共有229種物種，其中有25種物種是有毒物質，有17種物種是優先列管之(HAPs)有害污染物。離島工業區自7月至9月發生4大陳情事件，其中7月兩件分別檢出丙烯醛超過周界排放標準(2 ppb)，9月兩件六個點分別檢出二氯甲烷遠高於近二年陳情案採樣分析結果最高值(98.10.30新興國小)5.53ppb。另外藉由六輕查核工作進度會議及教育訓練的辦理，經由專家學長的經驗傳承，確實有助於提升對整體六輕空氣污染管制的執行績效，執行人員較能具體掌握六輕全廠揮發性有機物的合理排放量，使本年度各項工作能順利完成並獲致預期成果，進而有效協助提昇整體空氣品質管理之成效。
中文關鍵字	委員現場查核、質量平衡、water 9

中文摘要

「98年度加強離島工業區空氣污染物整合執行計畫」自98年11月2日至99年11月1日止，計12個月，已達到彙整及確認離島工業區近三年排放量前10大製程及其空氣污染物排放量、10廠次委員現場查核、質量平衡方式確認近三年來排放量前20大製程及4場次教育訓練、5場次查核進度會議、掌握儲槽之逸散性污染源排放量推估方法、完成六輕南亞麥寮廢水廠、海豐廢水廠、長春大連綜合廢水廠、合成酚、對苯二甲酸、台塑石化等廢水廠之water 9模式模擬推估及21廠油漆塗裝作業排放量推估、配合離島許可計畫陳情案件進行廠區異味採樣分析36件次等執行目標。排放量前10大製程，由近三年各種排放比對結果各種排放量皆小於許可證核發的排放量，空污費申報資料完整性及一致性尚佳，由檢測資料比對結果，97年度發電廠硫氧化物排放濃度有升高情形，經查係因受景氣影響，為減少燃料成本劣質煤使用比例增加之故；10廠次20個製程的委員現場查核結果及質能平衡，質能平衡閉合性良好，但仍存在中間產品、副原料未申報及廢氣燃燒塔操作法規符合度與實際防制效率的疑慮等問題；目前六輕儲槽之排放量推估方法，經驗證已確認是依據AP-42第五版計算，但部分儲槽經由離島VOC計畫實測結果證實仍有洩漏及實際蒸氣壓與設計蒸氣壓有差異，這將影響排放量推估結果，因此有必要加以驗證；water 9模式模擬推估廢水處理廠VOCs排放量與SCCcod計算結果比對，不如預期water 9推估結果絕對高於SCCcod計算結果，其原因為water 9推估結果主要受到廢水中VOCs物種及濃度、廢水量、處理單元規模等因素影響，因此其推估結果較SCCcod計算結果客觀，但整體推估結果仍大於SCCcod計算結果；21大廠98年油漆及調薄劑用量總計為1166噸，依據環保署96年年度排放更新引用排放係數計算結果為601噸，另依SCC排放係數及台灣區塗料油漆工業同業公會所提出的排放係數個別予以計算結果分別為898噸與700噸，若以離島工業區現行使用油漆固形物比例及調薄劑比例，建議以環保署96年年度排放更新引用排放係數計算較為合理；異味採樣分析本年度已完成31點次陳情案件，12點次污染源製程區及周界採樣分析作業，而31點次陳情案件中有26點次是本計畫負責送驗，統計陳情案件發生的風向以北到西北佔61%最多，其次為西到西南佔16%，陳情頻率最高者為新興國小19%，其次為海豐分校13%，統計陳情案件所測得31種物種中非六輕各廠申報的物種占4種，而31種物種中烷類物種占39％為最多，其次為苯類占23％。指紋資料調查周界採樣分析結果檢測出物種中，有九成幾乎於排放管道成份分析中可測得，其他為製程原料與反應生成物。另從離島工業區所提供排放管道成分析結果共有229種物種，其中有25種物種是有毒物質，有17種物種是優先列管之(HAPs)有害污染物。離島工業區自7月至9月發生4大陳情事件，其中7月兩件分別檢出丙烯醛超過周界排放標準(2 ppb)，9月兩件六個點分別檢出二氯甲烷遠高於近二年陳情案採樣分析結果最高值(98.10.30新興國小)5.53ppb。另外藉由六輕查核工作進度會議及教育訓練的辦理，經由專家學長的經驗傳承，確實有助於提升對整體六輕空氣污染管制的執行績效，執行人員較能具體掌握六輕全廠揮發性有機物的合理排放量，使本年度各項工作能順利完成並獲致預期成果，進而有效協助提昇整體空氣品質管理之成效。

中文關鍵字

委員現場查核、質量平衡、water 9

類型	檔名	檔案大小	說明	最新版公開日期
期末報告	98年度加強離島工業區空氣污染物整合計畫期末報告.pdf	19MB		2011/3/1 上午 12:00:00

摘要	According to the comparing results between various emissions in last three years, all amounts are less than the allowance of permit in the top 10 emission processes. The integrity and consistency of reported data of air pollution fee are comparatively good. As the comparing results of testing data showed, the SOx emission concentration of power plant increased in 2008. Due to the impact of economic downturn, the usage rate of lower-quality coals increased for decreasing the fuel cost. 10 plants 20 members process the results of committee site inspections, Results, material and energy balance closed well, but there are intermediate products, raw materials undeclared vice flare operating regulations and conformity with the actual control efficiency concerns and other issues; Currently Sixth Naphtha tank emission estimation method is based on proven has confirmed that the fifth edition of AP-42 calculation, AP-42 fifth edition and fourth edition of the most important difference is that the loss of sealing the edge of the impact of wind, the Sixth Naphtha floating roof tanks are stamped, is not affected by wind speed, and therefore, Fourth Edition or the fifth edition, as calculated on the basis of their results are consistent, but some of the Islands by the VOCs storage tank program and the experimental results confirm that there are leaks and design of the actual vapor pressure vapor pressure are different, this will affect the results of emission estimation, it is need to be verified; water 9 wastewater treatment plant modeling and simulation to estimate the amount of VOCs emissions calculated with SCC cod comparison of the predicted results as expected water 9 SCC cod result is far greater than its estimated results due to water 9 VOCs mainly by wastewater species and concentration, waste water, processing unit scale factors, so the predicted results calculated over SCC cod objective, but the overall result is still greater than the estimated results SCC cod ; 21 manufacturers and 2009 of paint thinner total dosage 1166 tons, according to EPA 96 emission factor annual emission update the reference evaluates to 601 tons, and the other in accordance with SCC emission factor and Taiwan Paint Industry Association paints made by the individual emission factors were calculated to be 898 tons and 700 tons, if to offshore industrial zone and the proportion of the existing use of paint thinner agent solids ratio of 96 recommendations to EPA emission factor annual emission update the reference to calculate a more reasonable; Odor sampling and analysis for the year has completed 31 complaint cases, 12 item sources of pollution process area and perimeter sampling and analysis operations, statistics of the cases not measured 31 kinds of species, not the Sixth Naphtha the plant to declare the species accounted for 4 species and 31 species of methane accounted for 39% of species, followed by 23% benzene. The perimeter of the fingerprint data to investigate the results of sample analysis to detect species Ninety per cent of component analysis is almost in the discharge pipe can be measured, the other to process raw materials and reaction products. With the analysis results of the discharge pipe which provided by the outlying islands industrial park, there were 225 kinds of substances in total. Within those substances, there were 25 toxic and 17 were the priority regulated of hazard air pollutants (HAPs). Four petitions were proposed in outlying industrial park since July to September. With the two in July, acrolein were found out, exceeding the peripheral boundary emissions standard (2 ppb) while in two cases in September methylene chloride in six locations were highest in sample analyzing results of petition cases in last two years. Besides, by the means of Sixth Naphtha Audit work scheduling meeting and the training courses taught by the experienced experts is conducive to improve the overall performance of the air pollution control of Sixth Naphtha. Enforcement agents can grasp the reasonable emissions of volatile organic compounds of the whole plant of Sixth Naphtha better. It’s not only helpful to succeed in the every work of this year to achieve anticipated target, but also good for improve effect of overall air quality management.
英文關鍵字	Committee on-site examination, mass balance, water 9

摘要

According to the comparing results between various emissions in last three years, all amounts are less than the allowance of permit in the top 10 emission processes. The integrity and consistency of reported data of air pollution fee are comparatively good. As the comparing results of testing data showed, the SOx emission concentration of power plant increased in 2008. Due to the impact of economic downturn, the usage rate of lower-quality coals increased for decreasing the fuel cost. 10 plants 20 members process the results of committee site inspections, Results, material and energy balance closed well, but there are intermediate products, raw materials undeclared vice flare operating regulations and conformity with the actual control efficiency concerns and other issues; Currently Sixth Naphtha tank emission estimation method is based on proven has confirmed that the fifth edition of AP-42 calculation, AP-42 fifth edition and fourth edition of the most important difference is that the loss of sealing the edge of the impact of wind, the Sixth Naphtha floating roof tanks are stamped, is not affected by wind speed, and therefore, Fourth Edition or the fifth edition, as calculated on the basis of their results are consistent, but some of the Islands by the VOCs storage tank program and the experimental results confirm that there are leaks and design of the actual vapor pressure vapor pressure are different, this will affect the results of emission estimation, it is need to be verified; water 9 wastewater treatment plant modeling and simulation to estimate the amount of VOCs emissions calculated with SCC cod comparison of the predicted results as expected water 9 SCC cod result is far greater than its estimated results due to water 9 VOCs mainly by wastewater species and concentration, waste water, processing unit scale factors, so the predicted results calculated over SCC cod objective, but the overall result is still greater than the estimated results SCC cod ; 21 manufacturers and 2009 of paint thinner total dosage 1166 tons, according to EPA 96 emission factor annual emission update the reference evaluates to 601 tons, and the other in accordance with SCC emission factor and Taiwan Paint Industry Association paints made by the individual emission factors were calculated to be 898 tons and 700 tons, if to offshore industrial zone and the proportion of the existing use of paint thinner agent solids ratio of 96 recommendations to EPA emission factor annual emission update the reference to calculate a more reasonable; Odor sampling and analysis for the year has completed 31 complaint cases, 12 item sources of pollution process area and perimeter sampling and analysis operations, statistics of the cases not measured 31 kinds of species, not the Sixth Naphtha the plant to declare the species accounted for 4 species and 31 species of methane accounted for 39% of species, followed by 23% benzene. The perimeter of the fingerprint data to investigate the results of sample analysis to detect species Ninety per cent of component analysis is almost in the discharge pipe can be measured, the other to process raw materials and reaction products. With the analysis results of the discharge pipe which provided by the outlying islands industrial park, there were 225 kinds of substances in total. Within those substances, there were 25 toxic and 17 were the priority regulated of hazard air pollutants (HAPs). Four petitions were proposed in outlying industrial park since July to September. With the two in July, acrolein were found out, exceeding the peripheral boundary emissions standard (2 ppb) while in two cases in September methylene chloride in six locations were highest in sample analyzing results of petition cases in last two years. Besides, by the means of Sixth Naphtha Audit work scheduling meeting and the training courses taught by the experienced experts is conducive to improve the overall performance of the air pollution control of Sixth Naphtha. Enforcement agents can grasp the reasonable emissions of volatile organic compounds of the whole plant of Sixth Naphtha better. It’s not only helpful to succeed in the every work of this year to achieve anticipated target, but also good for improve effect of overall air quality management.

英文關鍵字

Committee on-site examination, mass balance, water 9