環保專案成果報告查詢系統

專案計畫編號	EPA-101-1602-02-03
經費年度	101
計畫經費	1,960 千元
專案開始日期	2012/03/20
專案結束日期	2012/12/31
專案主持人	王介亨
主辦單位	環檢所
承辦人	王振興
執行單位	工業技術研究院綠能所
專案分類	環境監測及檢測
中文關鍵字	工業區;周界;有機空氣污染物
英文關鍵字	Industrial area;ambient;organic air pollutants
協同主持人	蕭祥憲
共同主持人
計畫聯絡人	王介亨
計畫聯絡電話	035-732942#
計畫聯絡信箱	chwang@itri.org.tw

中文摘要	本計畫目標是開發工業區空氣中環氧氯丙烷、乙酸丁酯、丙烯酸乙酯、丙烯酸丁酯、二氯甲醚、硫酸乙酯、二異氰酸甲苯和二異氰酸二苯甲烷等8項空氣污染物調查技術，以提供符合環保署方法格式規範之相關調查技術程序之參考依據。本計畫依照去年度執行排放管道中同樣8種成分之開發經驗，由於8項空氣污染物的特性不一，其中沸點範圍(99~251 ℃)與飽和蒸氣壓(13~0.00014 mmHg) 差異頗大，在空氣中或中以氣態、霧滴或粒狀物等型態存在，因此在研究初期在實驗上並非如預期8項空氣污染物皆能以不銹鋼採樣罐採樣搭配GC-MS分析；本計畫建立之方法中，環氧氯丙烷、乙酸丁酯、丙烯酸乙酯和丙烯酸丁酯等4項空氣污染物以不銹鋼採樣罐採樣經由GC-MS分析；硫酸乙酯和二氯甲醚以吸附管採樣搭配GC-MS進行採樣分析；二異氰酸甲苯和二異氰酸二苯甲烷以衝擊瓶採樣注射液相層析儀進行分析，本計畫以上述三種調查技術建立，完成包括方法之品保規範，包括準確性、偵測極限、精密度及重覆性等，結果顯示本計畫建立之三種技術均可適用於現行環保署管制標準，並提供符合環保署方法格式規範之調查技術程序，及將8項空氣污染物之調查技術擴散至環檢所。
中文關鍵字	工業區;周界;有機空氣污染物

中文摘要

本計畫目標是開發工業區空氣中環氧氯丙烷、乙酸丁酯、丙烯酸乙酯、丙烯酸丁酯、二氯甲醚、硫酸乙酯、二異氰酸甲苯和二異氰酸二苯甲烷等8項空氣污染物調查技術，以提供符合環保署方法格式規範之相關調查技術程序之參考依據。本計畫依照去年度執行排放管道中同樣8種成分之開發經驗，由於8項空氣污染物的特性不一，其中沸點範圍(99~251 ℃)與飽和蒸氣壓(13~0.00014 mmHg) 差異頗大，在空氣中或中以氣態、霧滴或粒狀物等型態存在，因此在研究初期在實驗上並非如預期8項空氣污染物皆能以不銹鋼採樣罐採樣搭配GC-MS分析；本計畫建立之方法中，環氧氯丙烷、乙酸丁酯、丙烯酸乙酯和丙烯酸丁酯等4項空氣污染物以不銹鋼採樣罐採樣經由GC-MS分析；硫酸乙酯和二氯甲醚以吸附管採樣搭配GC-MS進行採樣分析；二異氰酸甲苯和二異氰酸二苯甲烷以衝擊瓶採樣注射液相層析儀進行分析，本計畫以上述三種調查技術建立，完成包括方法之品保規範，包括準確性、偵測極限、精密度及重覆性等，結果顯示本計畫建立之三種技術均可適用於現行環保署管制標準，並提供符合環保署方法格式規範之調查技術程序，及將8項空氣污染物之調查技術擴散至環檢所。

中文關鍵字

工業區;周界;有機空氣污染物

類型	檔名	檔案大小	說明	最新版公開日期
期末報告	1.建立周界環氧氯丙烷等有機空氣污染物之調查技術開發_期末報告(定稿).pdf	3MB		2013/2/1 上午 12:00:00

摘要	The major objective of the project aims to develop sampling and analysis technology of organic air pollutants (1-Chloro-2,3-epoxypropane, bis-Chloromethyl Ether, n-Buthyl Acetate, Ethyl Acrylate, Toluene Diisocyanate, Methylene Disphenyl Isocyanate, Diethyl Sulfate, n-Butyl Acrylate ) in ambient and provide test methods established to Environmental Analysis Laboratory, EPA. Follow the previous study, we expected to analysis all organic air pollutants by sampling cans and GC-MS analysis system. However, there are many differences of 8 air pollutants, like the boiling point range of 99 ~ 251 ℃ and saturated steam pressure of 13 ~ 0.00014mmHg and with gas, mist or particulate type exist in ambient. Therefore, in this study, assess epichlorohydrin(ECH), butyl acetate(BA), ethyl acrylate(EA) and butyl acrylate(n-BA) could be analysis by sampling with cans, analyzing by GC-MS method. diethyl sulfate(DES) and bis-Chloromethyl Ether(BCME) that will try to be sampled by sampling tubes and analyzed with GC-MS. Toluene diisocyanate, and methylene disphenyl Isocyanate will be reacted with derivation reagent in impinger and analyzed by HPLC. We developed 8 kinds of air pollutants analyse technology, including methods of quality assurance standards, calibration, detection limits, sample storage time, precision accuracy, etc.,This project demonstrated the detection limits of these developed methods can match the currently EPA regulations for ambient air, and furthermore to provide draft standard operation procedure for EPA.
英文關鍵字	Industrial area;ambient;organic air pollutants

摘要

The major objective of the project aims to develop sampling and analysis technology of organic air pollutants (1-Chloro-2,3-epoxypropane, bis-Chloromethyl Ether, n-Buthyl Acetate, Ethyl Acrylate, Toluene Diisocyanate, Methylene Disphenyl Isocyanate, Diethyl Sulfate, n-Butyl Acrylate ) in ambient and provide test methods established to Environmental Analysis Laboratory, EPA. Follow the previous study, we expected to analysis all organic air pollutants by sampling cans and GC-MS analysis system. However, there are many differences of 8 air pollutants, like the boiling point range of 99 ~ 251 ℃ and saturated steam pressure of 13 ~ 0.00014mmHg and with gas, mist or particulate type exist in ambient. Therefore, in this study, assess epichlorohydrin(ECH), butyl acetate(BA), ethyl acrylate(EA) and butyl acrylate(n-BA) could be analysis by sampling with cans, analyzing by GC-MS method. diethyl sulfate(DES) and bis-Chloromethyl Ether(BCME) that will try to be sampled by sampling tubes and analyzed with GC-MS. Toluene diisocyanate, and methylene disphenyl Isocyanate will be reacted with derivation reagent in impinger and analyzed by HPLC. We developed 8 kinds of air pollutants analyse technology, including methods of quality assurance standards, calibration, detection limits, sample storage time, precision accuracy, etc.,This project demonstrated the detection limits of these developed methods can match the currently EPA regulations for ambient air, and furthermore to provide draft standard operation procedure for EPA.

英文關鍵字

Industrial area;ambient;organic air pollutants