環保專案成果報告查詢系統

專案計畫編號	EPA-102-E3S2-02-01
經費年度	102
計畫經費	1,430 千元
專案開始日期	2013/03/05
專案結束日期	2013/12/31
專案主持人	宋隆佑
主辦單位	環檢所
承辦人	李慈毅
執行單位	工業技術研究院
專案分類	大氣空氣
中文關鍵字	周界空氣;胺類;臭異味
英文關鍵字	ambient air;amines;odor
協同主持人	林敦慧
共同主持人
計畫聯絡人	宋隆佑
計畫聯絡電話	03-5732669#
計畫聯絡信箱	leosung@itri.org.tw

中文摘要	本計畫主要目的是開發周界中胺類污染物分析方法，並且探討其實施線上監測的可能性。收集文獻資料比較各種分析方法，發現氣相層析、液相層析、離子層析等方法是常用於胺類成份分析的技術。氣相層析和液相層析需要先生成衍生物才有良好的分析效果，不利於開發胺類線上監測的技術，因此本計畫選擇使用離子層析為測試的分析技術。選擇甲胺、二甲胺、乙胺、二乙胺、異丙胺、和正丙胺等六種化合物作為測試分析方法的目標物種。使用離子層析方法，可以將選定的物種有效地分離並偵測。各成分二次曲線標準檢量線的決定係數 R2 值可達 0.998 以上。測試結果發現使用 impinger 採樣有良好的效果。使用impinger 採樣結合IC分析的設備已有商業化產品，可應用於外界觸發啟動採樣。
中文關鍵字	周界空氣;胺類;臭異味

中文摘要

本計畫主要目的是開發周界中胺類污染物分析方法，並且探討其實施線上監測的可能性。收集文獻資料比較各種分析方法，發現氣相層析、液相層析、離子層析等方法是常用於胺類成份分析的技術。氣相層析和液相層析需要先生成衍生物才有良好的分析效果，不利於開發胺類線上監測的技術，因此本計畫選擇使用離子層析為測試的分析技術。選擇甲胺、二甲胺、乙胺、二乙胺、異丙胺、和正丙胺等六種化合物作為測試分析方法的目標物種。使用離子層析方法，可以將選定的物種有效地分離並偵測。各成分二次曲線標準檢量線的決定係數 R2 值可達 0.998 以上。測試結果發現使用 impinger 採樣有良好的效果。使用impinger 採樣結合IC分析的設備已有商業化產品，可應用於外界觸發啟動採樣。

中文關鍵字

周界空氣;胺類;臭異味

類型	檔名	檔案大小	說明	最新版公開日期
期末報告	空氣中含氮異味物質之線上監測技術之開發_期末報告.pdf	5MB	期末報告定稿本	2014/2/1 上午 12:00:00

摘要	The major objective of the project is to develop the sampling and analysis technology of ambient volatile amine pollutants. The capability of on-line amines monitoring issue is also discussed. Most analytical procedures reported for the analysis of amines feature separation methods. Gas chromatography (GC), High-performance liquid chromatography (HPLC), and ion chromatography (IC) are discussed in the determination of amines. Derivatization of amines is frequently employed to GC and HPLC which makes it disadvantage to build up an automated system for on-line monitoring. IC was chosen for this study because this technique allows separation of the amines without the need for tedious and time-consuming derivatization reactions. Six chemicals, including methylamine, dimethylamine, ethylamine, isopropylamine, propylamine, and diethylamine were selected as the target compounds for test the analysis method. All the target compounds were successfully separated by ion chromatography and detected. The coefficient of determination (R2) for calibration curve of each compound was better than 0.998. The efficient impinger technique was applied for the air sampling. Impinge/IC is possible to act as a trigger driven unit for amine motoring. Commercialized on-line impinger/IC is available now.
英文關鍵字	ambient air;amines;odor

摘要

The major objective of the project is to develop the sampling and analysis technology of ambient volatile amine pollutants. The capability of on-line amines monitoring issue is also discussed. Most analytical procedures reported for the analysis of amines feature separation methods. Gas chromatography (GC), High-performance liquid chromatography (HPLC), and ion chromatography (IC) are discussed in the determination of amines. Derivatization of amines is frequently employed to GC and HPLC which makes it disadvantage to build up an automated system for on-line monitoring. IC was chosen for this study because this technique allows separation of the amines without the need for tedious and time-consuming derivatization reactions. Six chemicals, including methylamine, dimethylamine, ethylamine, isopropylamine, propylamine, and diethylamine were selected as the target compounds for test the analysis method. All the target compounds were successfully separated by ion chromatography and detected. The coefficient of determination (R2) for calibration curve of each compound was better than 0.998. The efficient impinger technique was applied for the air sampling. Impinge/IC is possible to act as a trigger driven unit for amine motoring. Commercialized on-line impinger/IC is available now.

英文關鍵字

ambient air;amines;odor