環保專案成果報告查詢系統

專案計畫編號	EPA-102-E3S3-02-02
經費年度	102
計畫經費	1,970 千元
專案開始日期	2013/02/27
專案結束日期	2013/12/31
專案主持人	黃許麗娟
主辦單位	環檢所
承辦人	曹明浙
執行單位	工業技術研究院綠能與環境研究所
專案分類	環境監測及檢測
中文關鍵字	污泥、特性分析、鑑識技術
英文關鍵字	sludge、characteristic analysis、forensic technology
協同主持人	方孟德
共同主持人
計畫聯絡人	黃許麗娟
計畫聯絡電話	03-5743931#
計畫聯絡信箱	lihjiuansheu@itri.org.tw

中文摘要	本計畫研究內容主要針對皮革業及石化業污泥特性進行鑑識技術開發研究，計畫執行過程首先蒐集彙整相關皮革業及石化業製程、使用原物料、添加試藥、水污染處理方式、使用設施及操作條件，與國內外污泥相關鑑識技術，及彙整各種相關污泥鑑識結果如：印刷電路板(PCB)污泥、氟化鈣污泥、皮革污泥、石化業污泥的特性指標，並引用至本計畫污泥特性鑑識技術建立之參考。本研究計畫在執行皮革業及石化業污泥特性鑑識及特性指標建置部分，係採用電子顯微鏡(SEM)觀察外觀形狀及EDX檢測特性成份，以XRD檢測污泥樣品之結晶性及晶相結構，與使用XRF(或EDX)分析，訂出主成份、次要成份、微量成份，與使用GC/MS快速測定有機物之化合物種類，及以LC/Q-TOF定性高極性及水溶性有機化合物，與使用DNA分子生物檢測方法來鑑識污泥中的菌群組成結構與豐富度。由上述鑑識方法所得到的檢測結果彙整評析後，得到一個初步的皮革業及石化業之特性指標如下： 1.皮革業特性指標： •XRF：鉻、硫 •有機物：膽固醇Cholesterol、脫脂劑(Dipropylene glycol)、殺菌劑Phenol 、2-(methylthio)-Benzothiazole、 2.石化業特性指標： •XRF：無特性指標之金屬元素 •有機物：依各廠生產產品特性而定，特性指標如Cyclohexane、DOPs、PAHs、1,3-Dioxolane、Phthalic anhydride、可塑劑TOTM。此外在本研究計畫中也評估了LC/Q-TOF及DNA分子生物檢測方法應用在皮革業、石化業污泥鑑識之可行性評估，經評估結果可有效鑑識皮革業、石化業污泥中之有機酸、氨基酸、PEG脫脂劑及微生物菌種。
中文關鍵字	污泥、特性分析、鑑識技術

中文摘要

本計畫研究內容主要針對皮革業及石化業污泥特性進行鑑識技術開發研究，計畫執行過程首先蒐集彙整相關皮革業及石化業製程、使用原物料、添加試藥、水污染處理方式、使用設施及操作條件，與國內外污泥相關鑑識技術，及彙整各種相關污泥鑑識結果如：印刷電路板(PCB)污泥、氟化鈣污泥、皮革污泥、石化業污泥的特性指標，並引用至本計畫污泥特性鑑識技術建立之參考。本研究計畫在執行皮革業及石化業污泥特性鑑識及特性指標建置部分，係採用電子顯微鏡(SEM)觀察外觀形狀及EDX檢測特性成份，以XRD檢測污泥樣品之結晶性及晶相結構，與使用XRF(或EDX)分析，訂出主成份、次要成份、微量成份，與使用GC/MS快速測定有機物之化合物種類，及以LC/Q-TOF定性高極性及水溶性有機化合物，與使用DNA分子生物檢測方法來鑑識污泥中的菌群組成結構與豐富度。由上述鑑識方法所得到的檢測結果彙整評析後，得到一個初步的皮革業及石化業之特性指標如下： 1.皮革業特性指標： •XRF：鉻、硫 •有機物：膽固醇Cholesterol、脫脂劑(Dipropylene glycol)、殺菌劑Phenol 、2-(methylthio)-Benzothiazole、 2.石化業特性指標： •XRF：無特性指標之金屬元素 •有機物：依各廠生產產品特性而定，特性指標如Cyclohexane、DOPs、PAHs、1,3-Dioxolane、Phthalic anhydride、可塑劑TOTM。此外在本研究計畫中也評估了LC/Q-TOF及DNA分子生物檢測方法應用在皮革業、石化業污泥鑑識之可行性評估，經評估結果可有效鑑識皮革業、石化業污泥中之有機酸、氨基酸、PEG脫脂劑及微生物菌種。

中文關鍵字

污泥、特性分析、鑑識技術

類型	檔名	檔案大小	說明	最新版公開日期
期末報告	污泥行業別現況調查及鑑識計畫期末報告定稿版(公開版)docx.pdf	7MB		2014/3/1 上午 12:00:00

摘要	Abstract The purpose of this study was to develop the forensic technology of the sludge of the leather and petrochemical industries. The study collected the manufacture processes, raw materials used, chemicals added, wastewater treatment, facility and operation, related international and domestic information regarding the sludge forensics, and related information such as the sludge features of printed circuit board (PCB), calcium fluoride, leathering, and petrochemical industries. As for the sludge index establishment of the leather and petrochemical industries, SEM was used to observe the appearance, EDX was used to determine the characteristic constituents, XRD was used to analyze the crystalline structure, XRF (or EDX) was used to identify the primary, secondary, and trace constituents, GC/MS was used to determine the organic chemicals, LC/Q-TOF was used to identify highly polarized and water-soluble organic chemicals, and DNA analytical methods were used to determine the bacterial populations and abundances. Based on the results of the above analyses, the sludge characteristics of the leather and petrochemical industries can be summarized as follows: Leather industry •XRF: chromium, sulfur •Organic matters: cholesterol, degreasing agent (dipropylene glycol), bactericide, phenol, 2-(methylthio)-benzothiazole Petrochemical industry •XRF: no characteristic metals • Organic matters: Depending upon the products, it varies among cyclohexane, DOPs, PAHs, 1,3-dioxolane, phthalic anhydride, plasticizing agent TOTM. In addition, the feasibility study of using LC/Q-TOF and DNA analytical methods on leather and petrochemical industries. The results showed that the methods could be effectively used to identify organic acids, amino acids, PEG degreasing agent, and bacteria in the sludge of the leather and petrochemical industries.
英文關鍵字	sludge、characteristic analysis、forensic technology

摘要

Abstract The purpose of this study was to develop the forensic technology of the sludge of the leather and petrochemical industries. The study collected the manufacture processes, raw materials used, chemicals added, wastewater treatment, facility and operation, related international and domestic information regarding the sludge forensics, and related information such as the sludge features of printed circuit board (PCB), calcium fluoride, leathering, and petrochemical industries. As for the sludge index establishment of the leather and petrochemical industries, SEM was used to observe the appearance, EDX was used to determine the characteristic constituents, XRD was used to analyze the crystalline structure, XRF (or EDX) was used to identify the primary, secondary, and trace constituents, GC/MS was used to determine the organic chemicals, LC/Q-TOF was used to identify highly polarized and water-soluble organic chemicals, and DNA analytical methods were used to determine the bacterial populations and abundances. Based on the results of the above analyses, the sludge characteristics of the leather and petrochemical industries can be summarized as follows: Leather industry •XRF: chromium, sulfur •Organic matters: cholesterol, degreasing agent (dipropylene glycol), bactericide, phenol, 2-(methylthio)-benzothiazole Petrochemical industry •XRF: no characteristic metals • Organic matters: Depending upon the products, it varies among cyclohexane, DOPs, PAHs, 1,3-dioxolane, phthalic anhydride, plasticizing agent TOTM. In addition, the feasibility study of using LC/Q-TOF and DNA analytical methods on leather and petrochemical industries. The results showed that the methods could be effectively used to identify organic acids, amino acids, PEG degreasing agent, and bacteria in the sludge of the leather and petrochemical industries.

英文關鍵字

sludge、characteristic analysis、forensic technology