EPA-104-E3S4-02-03

104

2,780 千元

2015/03/17

2015/12/31

黃許麗娟

環檢所

王姿惠

工業技術研究院綠能與環境研究所

環境監測及檢測

污泥特性分析、FTIR＆Raman鑑識技術、印染業、化學製品製造業

Sludge characterization analysis、 FTIR ＆ Raman forensics、 printing and dyeing industry、 chemical manufacturing industry

黃許麗娟

03-5743931#

lihjiuansheu@itri.org.tw

本研究計畫目標主要為蒐集彙整國內外環境鑑識技術相關文獻，如GC/ IRMS、FTIR及拉曼光譜等鑑識技術，應用於污泥鑑識技術之開發與評估，及利用已開發之快速篩選與鑑識技術，配合開發GC/IRMS、FTIR及拉曼光譜等鑑識技術，應用在污泥特性指標物鑑識可行性評析，以建立適用於國內污泥特性指標物之鑑識程序及污泥鑑識技術評析報告。 本研究計畫依據計畫目標及工作內容規範在執行GC/IRMS、FTIR及拉曼鑑識技術開發部分，係參考國內外相關期刊論文所引用的GC/IRMS、FTIR及拉曼鑑識技術，應用在污泥、土壤、環境科學、食品來源或摻假辨識等待測物(或污染物)的檢測技術，來建立適用的樣品前處理及淨化方法與儀器分析條件和數據解析方法。本研究為開發及評估GC/IRMS、FTIR及拉曼鑑識技術應用在各行業別污泥特性指標物鑑識之可行性評估與確認部分，在本計畫中是選擇以印染業及化學製品製造業污泥為示範的對象，並搭配XRF、XRD、SEM/EDX、GC/MS等快速篩選方法，以建立印染業、化學製品製造業污泥中有機、無機類特性指標物的資料檔，和建置適用於國內污泥特性指標物的鑑識程序。 由本研究所建置的鑑識技術及印染業、化學製品製造業污泥的鑑識結果彙整評析後，得到一個初步的特性指標物如下所示： 1.印染業特性指標： • Cyclohexasiloxane, dodecamethyl-、Cycloheptasiloxane, tetradecamethyl-、C20~C34 ＆ cyclic alkane＆siloxane、Eicosane、Tricosane、Tetracosane、 Hexacosane、Octacosane、Tetradecanamide、Hexadecanamide、A(C2H4O)nB、A(C3H6O)nB、C20H23N3O(抗菌劑) 2. 化學製品製造業(染顏料業)特性指標： •Benzene, isocyanato-、Aniline、Benzenemethanamine、3,3'-Dichlorobenzidine、 Benzenamine, 4-chloro-2,5-dimethoxy-、1,1'-Biphenyl, 2,4'-dichloro-、1,1'-Biphenyl, 2,2',3,4-tetrachloro-、1,1'-Biphenyl, 2,2',4,4',5-pentachloro-、1,1'-Biphenyl, 2,3,3',4,5,6-hexachloro-(多氯聯苯)、Dibenzo[b,e][1,4]dioxin, 1,2,3,4-tetrachloro- ＆ isomer(戴奧辛)

污泥特性分析、FTIR＆Raman鑑識技術、印染業、化學製品製造業

環境鑑識技術開發研究印染業及化學品製造業建室技術開發與應用(期末報告1041222)定稿本.pdf

13MB

2016/2/1 上午 12:00:00

The purpose of this study was to collect documentary information regarding the forensic technology of GC/ IRMS, FTIR, and Raman. It also includes the development and assessment of the technologies with the developed fast screening for establishing the identification procedures with respect to sludge. The objectives of this study include the forensic technology development of GC/IRMS, FTIR, and Raman, which collects the research articles regarding these analytical methods. The applications of the analysis are in the fields of sludge, soil, environmental science, food source, and illegal substitution of food ingredients. The main portion of the information was to establish the sample pretreatment, purification, instrument condition, and data analysis. This study selected the sludge from the wastewater treatment of the printing and dyeing industry and chemical manufacturing industry. The fast screening with XRF, XRD, SEM/EDX, and GC/MS can be also coupled with the studied methods in order to build up the sludge database of these industries on organic and inorganic indicators. The database can be used to construct the forensic procedure. The following is the preliminary indicators: 1. For the printing and dyeing industry: Cyclohexasiloxane, dodecamethyl-, Cycloheptasiloxane, tetradecamethyl-, C20~C34 ＆ cyclic alkane ＆ siloxane, Eicosane, Tricosane, Tetracosane, Hexacosane, Octacosane, Tetradecanamide, Hexadecanamide, A(C2H4O)nB, A(C3H6O)nB, C20H23N3O (antibacterial agent) 2. For the chemical manufacturing industry: Benzene, isocyanato-, Aniline, Benzenemethanamine, 3,3'-Dichlorobenzidine, Benzenamine, 4-chloro-2,5-dimethoxy-, 1,1'-Biphenyl, 2,4'-dichloro-, 1,1'-Biphenyl, 2,2',3,4-tetrachloro-, 1,1'-Biphenyl, 2,2',4,4',5-pentachloro-, 1,1'-Biphenyl, 2,3,3',4,5,6-hexachloro-(PCB), Dibenzo[b,e][1,4]dioxin, 1,2,3,4-tetrachloro- ＆ isomer(dioxin)

Sludge characterization analysis、 FTIR ＆ Raman forensics、 printing and dyeing industry、 chemical manufacturing industry