環保專案成果報告查詢系統

專案計畫編號	EPA-105-E3S4-02-02
經費年度	105
計畫經費	3,500 千元
專案開始日期	2016/03/30
專案結束日期	2016/12/31
專案主持人	黃許麗娟
主辦單位	環檢所
承辦人	王姿惠
執行單位	工業技術研究院綠能與環境研究所
專案分類	環境監測及檢測
中文關鍵字	污泥、鑑識技術、再現性
英文關鍵字	Sediment、Forensic technology 、Reproducibility
協同主持人
共同主持人
計畫聯絡人	黃許麗娟
計畫聯絡電話	03-5743931#
計畫聯絡信箱	lihjiuansheu@itri.org.tw

中文摘要	本研究計畫目標為(一)、整合環境樣品採樣技術資訊，蒐集彙整及評析相關採樣技術與文獻資料，建立「環境鑑識採樣技術規範」草案。(二)、應用已開發之鑑識技術進行河川底泥相關樣品分析，協助建立底泥特定污染物鑑識技術。(三)、建立事業污泥特性指標物資料檔並進行再現性測試，運用統計軟體進行數據解析。(四)、編撰鑑識技術操作手冊。本研究計畫為完成計畫目標，針對建立「環境鑑識採樣技術規範」草案部分是參考美國、歐盟、澳洲等國之環境採樣技術及品管規範資料，初步研擬「環境樣品採集品質管制措施及規範」指引。在編撰事業單位產生廢棄物採樣方法草案、再利用廢棄物採樣方法草案及不明廢棄物採樣方法草案主要參考各國廢棄物之採樣規劃、採樣規畫考量因素及廢棄物採樣時之考量因素等相關資訊，在配合實務需求來編撰之。而在建立河川底泥特定污染物鑑識部分，則先收集河川底泥、水質污染背景和污染調查資料，在進行樣品採集分析和數據解析比對。在建立事業污泥特性指標物資料檔部分，則建置了101年~104年的LED、LCD、DRAM、皮革業、石化業、印刷電路板、被動電子元件、太陽能及印染業、化學製品製造業等產業的污泥特性指標物資料檔。在污泥特性指標物再現性測試部分，則選擇印染業、染顏料業及石化業廠家來進行污泥再現性測試，並由測試結果與既有資料庫進行比對評析，以了解各行業之污泥是否具有再現性。在編撰鑑識技術操作手冊部分，包含撰寫樣品前處理步驟、鑑識流程圖等資料，以作為棄置污泥產源追查及發展新穎鑑識技術之參考。由本研究成果已完成「環境鑑識採樣技術規範」草案及「鑑識技術操作手冊」，而在污泥再現性測試部分也顯示印染業、染顏料業及石化業的污泥具有再現性，其具有再現性的特性指標物如下所示： 1.染顏料業特性指標：鋇(Ba)、鍶(Sr)、硫酸鋇、3,3'-Dichlorobenzidine、2,2',5,5'-Tetrachlorobenzidine、1,1'-Biphenyl, 2,4'-dichloro-、1,1'-Biphenyl, 2,2',3,4-tetrachloro-、1,1'-Biphenyl, 2,2',4,4',5-pentachloro-、1,1'-Biphenyl, 2,3,3',4,5,6-hexachloro-(多氯聯苯)、戴奧辛類化合物。 2.印染業特性指標：A(C2H4O)nB、A(C3H6O)nB、C20H23N3O(抗菌劑)、C20H41NO2 3.石化業特性指標：例如苯酸、可塑劑：Benzoic Acid、Benzoic Acid,2-methyl-、Phthalic anhydride、Di-n-octyl phthalate、tri(2-Ethylhexyl)trimellitate(可塑劑TOTM)製程中間產物及塑化劑產品。油泥：2,3-dimethyl-Naphthalene、2-methyl-Phenanthrene、2-methyl-Anthracene、2-methyl-Pyrene、o-Terphenyl、1,4-dimethyl-Anthracene、1-methyl-Chrysene等多環芳香烴化合物(PAHs)。
中文關鍵字	污泥、鑑識技術、再現性

中文摘要

本研究計畫目標為(一)、整合環境樣品採樣技術資訊，蒐集彙整及評析相關採樣技術與文獻資料，建立「環境鑑識採樣技術規範」草案。(二)、應用已開發之鑑識技術進行河川底泥相關樣品分析，協助建立底泥特定污染物鑑識技術。(三)、建立事業污泥特性指標物資料檔並進行再現性測試，運用統計軟體進行數據解析。(四)、編撰鑑識技術操作手冊。本研究計畫為完成計畫目標，針對建立「環境鑑識採樣技術規範」草案部分是參考美國、歐盟、澳洲等國之環境採樣技術及品管規範資料，初步研擬「環境樣品採集品質管制措施及規範」指引。在編撰事業單位產生廢棄物採樣方法草案、再利用廢棄物採樣方法草案及不明廢棄物採樣方法草案主要參考各國廢棄物之採樣規劃、採樣規畫考量因素及廢棄物採樣時之考量因素等相關資訊，在配合實務需求來編撰之。而在建立河川底泥特定污染物鑑識部分，則先收集河川底泥、水質污染背景和污染調查資料，在進行樣品採集分析和數據解析比對。在建立事業污泥特性指標物資料檔部分，則建置了101年~104年的LED、LCD、DRAM、皮革業、石化業、印刷電路板、被動電子元件、太陽能及印染業、化學製品製造業等產業的污泥特性指標物資料檔。在污泥特性指標物再現性測試部分，則選擇印染業、染顏料業及石化業廠家來進行污泥再現性測試，並由測試結果與既有資料庫進行比對評析，以了解各行業之污泥是否具有再現性。在編撰鑑識技術操作手冊部分，包含撰寫樣品前處理步驟、鑑識流程圖等資料，以作為棄置污泥產源追查及發展新穎鑑識技術之參考。由本研究成果已完成「環境鑑識採樣技術規範」草案及「鑑識技術操作手冊」，而在污泥再現性測試部分也顯示印染業、染顏料業及石化業的污泥具有再現性，其具有再現性的特性指標物如下所示： 1.染顏料業特性指標：鋇(Ba)、鍶(Sr)、硫酸鋇、3,3'-Dichlorobenzidine、2,2',5,5'-Tetrachlorobenzidine、1,1'-Biphenyl, 2,4'-dichloro-、1,1'-Biphenyl, 2,2',3,4-tetrachloro-、1,1'-Biphenyl, 2,2',4,4',5-pentachloro-、1,1'-Biphenyl, 2,3,3',4,5,6-hexachloro-(多氯聯苯)、戴奧辛類化合物。 2.印染業特性指標：A(C2H4O)nB、A(C3H6O)nB、C20H23N3O(抗菌劑)、C20H41NO2 3.石化業特性指標：例如苯酸、可塑劑：Benzoic Acid、Benzoic Acid,2-methyl-、Phthalic anhydride、Di-n-octyl phthalate、tri(2-Ethylhexyl)trimellitate(可塑劑TOTM)製程中間產物及塑化劑產品。油泥：2,3-dimethyl-Naphthalene、2-methyl-Phenanthrene、2-methyl-Anthracene、2-methyl-Pyrene、o-Terphenyl、1,4-dimethyl-Anthracene、1-methyl-Chrysene等多環芳香烴化合物(PAHs)。

中文關鍵字

污泥、鑑識技術、再現性

類型	檔名	檔案大小	說明	最新版公開日期
期末報告	環境鑑識技術開發研究事業污泥鑑識技術平台建置與應用期末報告1051226(定稿本).pdf	11MB		2017/2/1 上午 12:00:00

摘要	The purposes of the project were (1) to integrate environmental sampling, including technology information of collection, integration and analyses, to establish the draft of 「Technical Guidance of Environmental Forensic Sampling」; (2) to utilize the existing technologies of river sediment forensic sampling to build forensic technology for targeted contaminants; (3) to build indicator chemical information of industrial sludge to test for representation with statistical analyses; (4) and to compile the forensic operation handbook. The draft of 「Technical Guidance of Environmental Forensic Sampling」consisted of the information of environmental sampling and quality control from the US, the EU, and Australia to compile the guidebook of 「Quality Control for Environmental Sampling」. With considering practical experience, information of waste sampling plan, planning considerations, and sampling considerations from various countries was incorporated to compile the drafts of Institution draft Sampling Methods for Industrial Waste Generators、Sampling Methods for Recycled Wastes draft and Sampling Methods for Unidentified Wastes draft. With respect to establishing forensics of river sediment on targeted contaminants, the information collection of river sediments, water pollution background information, and contamination investigation was done prior to sample collection, analyses, and data analyses. With respect to the establishment of the indicator information of industrial sludge, the data and information files were built for LED, LCD, DRAM, leathering, petrochemical, printed circuit board, passive electronic, solar energy, and fabrication between 2012 and 2015. With respect to the representation test, samples were taken from the industries of fabrication, dye manufacturing, and petrochemical for analyses and the results were compared with the existing data in the database. With respect to the handbook compilation, sample pretreatment procedures and forensic procedure flowchart were included in order to track the contamination source and develop new forensic technologies. The draft of 「Technical Guidance of Environmental Forensic Sampling」 and 「Operational Handbook of Environmental Forensic Technology」 were compiled. The results of representation test showed the sludge of fabrication, dye manufacturing, and petrochemical was positively representable, and the representable indicators are as follows: 1.Dye manufacturing: Ba, Sr, barium sulfate, 3,3'-Dichlorobenzidine, 2,2',5,5'-Tetrachlorobenzidine, 1,1'-Biphenyl, 2,4'-dichloro-, 1,1'-Biphenyl, 2,2',3,4-tetrachloro-, 1,1'-Biphenyl, 2,2',4,4',5-pentachloro-, 1,1'-Biphenyl, 2,3,3',4,5,6-hexachloro-(polychlorinated benzene), Dioxin isomers 2.Fabrication industry: A(C2H4O)nB, A(C3H6O)nB, C20H23N3O (antibacterial agent), C20H41NO2 3.Petrochemical industry: Phthalic Anhydride(PA)、Plasticizers ：Benzoic Acid, Benzoic Acid,2-methyl-, Phthalic anhydride, Di-n-octyl phthalate, tri(2-Ethylhexyl)trimellitate (TOTM) Oil sludge:2,3-dimethyl-Naphthalene, 2-methyl-Phenanthrene, 2-methyl-Anthracene, 2-methyl-Pyrene, o-Terphenyl, 1,4-dimethyl-Anthracene, 1-methyl-Chrysene (PAHs)
英文關鍵字	Sediment、Forensic technology 、Reproducibility

摘要

The purposes of the project were (1) to integrate environmental sampling, including technology information of collection, integration and analyses, to establish the draft of 「Technical Guidance of Environmental Forensic Sampling」; (2) to utilize the existing technologies of river sediment forensic sampling to build forensic technology for targeted contaminants; (3) to build indicator chemical information of industrial sludge to test for representation with statistical analyses; (4) and to compile the forensic operation handbook. The draft of 「Technical Guidance of Environmental Forensic Sampling」consisted of the information of environmental sampling and quality control from the US, the EU, and Australia to compile the guidebook of 「Quality Control for Environmental Sampling」. With considering practical experience, information of waste sampling plan, planning considerations, and sampling considerations from various countries was incorporated to compile the drafts of Institution draft Sampling Methods for Industrial Waste Generators、Sampling Methods for Recycled Wastes draft and Sampling Methods for Unidentified Wastes draft. With respect to establishing forensics of river sediment on targeted contaminants, the information collection of river sediments, water pollution background information, and contamination investigation was done prior to sample collection, analyses, and data analyses. With respect to the establishment of the indicator information of industrial sludge, the data and information files were built for LED, LCD, DRAM, leathering, petrochemical, printed circuit board, passive electronic, solar energy, and fabrication between 2012 and 2015. With respect to the representation test, samples were taken from the industries of fabrication, dye manufacturing, and petrochemical for analyses and the results were compared with the existing data in the database. With respect to the handbook compilation, sample pretreatment procedures and forensic procedure flowchart were included in order to track the contamination source and develop new forensic technologies. The draft of 「Technical Guidance of Environmental Forensic Sampling」 and 「Operational Handbook of Environmental Forensic Technology」 were compiled. The results of representation test showed the sludge of fabrication, dye manufacturing, and petrochemical was positively representable, and the representable indicators are as follows: 1.Dye manufacturing: Ba, Sr, barium sulfate, 3,3'-Dichlorobenzidine, 2,2',5,5'-Tetrachlorobenzidine, 1,1'-Biphenyl, 2,4'-dichloro-, 1,1'-Biphenyl, 2,2',3,4-tetrachloro-, 1,1'-Biphenyl, 2,2',4,4',5-pentachloro-, 1,1'-Biphenyl, 2,3,3',4,5,6-hexachloro-(polychlorinated benzene), Dioxin isomers 2.Fabrication industry: A(C2H4O)nB, A(C3H6O)nB, C20H23N3O (antibacterial agent), C20H41NO2 3.Petrochemical industry: Phthalic Anhydride(PA)、Plasticizers ：Benzoic Acid, Benzoic Acid,2-methyl-, Phthalic anhydride, Di-n-octyl phthalate, tri(2-Ethylhexyl)trimellitate (TOTM) Oil sludge:2,3-dimethyl-Naphthalene, 2-methyl-Phenanthrene, 2-methyl-Anthracene, 2-methyl-Pyrene, o-Terphenyl, 1,4-dimethyl-Anthracene, 1-methyl-Chrysene (PAHs)

英文關鍵字

Sediment、Forensic technology 、Reproducibility