環保專案成果報告查詢系統

專案計畫編號
經費年度	107
計畫經費	2,980 千元
預算科目	空氣品質監測
專案開始日期	2018/01/27
專案結束日期	2019/01/31
專案主持人	賴進興教授
主辦單位	監資處
承辦人	程凱麟
執行單位	財團法人成大研究發展基金會
專案分類	環境監測及檢測
中文關鍵字	有害空氣污染物、環境監測、監測網
英文關鍵字	Hazardous Air Pollutants, Environmental Monitoring, Air Monitoring Network
協同主持人
共同主持人	吳義林教授；林清和教授
計畫聯絡人	邱慧真
計畫聯絡電話	06-2386764#
計畫聯絡信箱	niki@cs.ncku.edu.tw

中文摘要	本計畫之目標包括彙整先進國家有害空氣污染物環境監測策略措施、彙整29種有害空氣污染物之環境監測方法、由光化學評估測站及實地採樣數據，分析臺灣有害空氣污染物濃度特徵及規劃有害空氣污染物環境監測站位置。主要收集美國環保署歸類為空氣毒物的計畫規範，可分成國家毒性氣體趨勢監測網(NATTs)、城市空氣毒物監測計畫(UATMP)和社區規模空氣毒物周界監測(CSATAM)等等。彙整他國執行HAPs周界監測時有其不同之監測目標、監測項目、監測站位置等等，包括來自美國環保署(USEPA)、歐洲空氣污染物長程傳輸監測與評估合作計畫(EMEP)等國家所執行之HAPs環境監測計畫之資料，以作為我國監測網規劃之參考。本研究彙整多項HAPs之監測方法，彙整之方法涵蓋揮發性有機物、汞與其他重金屬之採樣分析方法。彙整全台光化測站及特殊工業區監測站數據，挑選出第一階段管制物種，分析其歷年濃度變化特徵，光化測站歷年之苯、甲苯、乙苯及二甲苯之濃度中位數變化，大多呈逐年下降，除小港外各站於107年有最低值。整理105至107年特殊性工業區測站數據，自動監測之各物種中位數，大致呈現逐年降低之趨勢。於高雄進行五處至少連續七天之實地採樣，分析臺灣HAPs濃度特徵並進行VOCs和重金屬不同採樣分析方法之比對，VOCs使用MiTAP自動儀器及不銹鋼筒手動方法進行採樣；重金屬自動監測採用Xact 625i，手動採樣使用開面式採樣器；甲乙醛採用LpDNPH-Cartridge以化學吸附方法進行樣品蒐集；石綿使用三件式濾紙匣，多氯聯苯則是用PUF高量採樣器。數據結果顯示，各站VOCs日平均濃度多以甲苯、間對二甲苯最高，各站重金屬日平均濃度多以鉛為最高。本計畫目前使用TEDS10全台各行業別之 PM及THC排放量資料，篩選出排放量前90%之行業別，並由Speciate4.5資料庫，將篩選出之各行業別代碼、車種代碼及面源代碼分別找出相對應之指紋資料，以進行後續排放量推估工作。將推估之各行業排放量，將其以各縣市進行劃分，並利用Industrial Source Complex (ISC)進行模式模擬，由於物種數量較多，彼此間的年平均增量濃度分布皆不盡相同，故將增量濃度換算為健康風險評估中的致癌風險值，並將各物種進行加總為總致癌風險值，藉此用來分析有害空氣污染物環境監測站最適位置。
中文關鍵字	有害空氣污染物、環境監測、監測網

中文摘要

本計畫之目標包括彙整先進國家有害空氣污染物環境監測策略措施、彙整29種有害空氣污染物之環境監測方法、由光化學評估測站及實地採樣數據，分析臺灣有害空氣污染物濃度特徵及規劃有害空氣污染物環境監測站位置。主要收集美國環保署歸類為空氣毒物的計畫規範，可分成國家毒性氣體趨勢監測網(NATTs)、城市空氣毒物監測計畫(UATMP)和社區規模空氣毒物周界監測(CSATAM)等等。彙整他國執行HAPs周界監測時有其不同之監測目標、監測項目、監測站位置等等，包括來自美國環保署(USEPA)、歐洲空氣污染物長程傳輸監測與評估合作計畫(EMEP)等國家所執行之HAPs環境監測計畫之資料，以作為我國監測網規劃之參考。本研究彙整多項HAPs之監測方法，彙整之方法涵蓋揮發性有機物、汞與其他重金屬之採樣分析方法。彙整全台光化測站及特殊工業區監測站數據，挑選出第一階段管制物種，分析其歷年濃度變化特徵，光化測站歷年之苯、甲苯、乙苯及二甲苯之濃度中位數變化，大多呈逐年下降，除小港外各站於107年有最低值。整理105至107年特殊性工業區測站數據，自動監測之各物種中位數，大致呈現逐年降低之趨勢。於高雄進行五處至少連續七天之實地採樣，分析臺灣HAPs濃度特徵並進行VOCs和重金屬不同採樣分析方法之比對，VOCs使用MiTAP自動儀器及不銹鋼筒手動方法進行採樣；重金屬自動監測採用Xact 625i，手動採樣使用開面式採樣器；甲乙醛採用LpDNPH-Cartridge以化學吸附方法進行樣品蒐集；石綿使用三件式濾紙匣，多氯聯苯則是用PUF高量採樣器。數據結果顯示，各站VOCs日平均濃度多以甲苯、間對二甲苯最高，各站重金屬日平均濃度多以鉛為最高。本計畫目前使用TEDS10全台各行業別之 PM及THC排放量資料，篩選出排放量前90%之行業別，並由Speciate4.5資料庫，將篩選出之各行業別代碼、車種代碼及面源代碼分別找出相對應之指紋資料，以進行後續排放量推估工作。將推估之各行業排放量，將其以各縣市進行劃分，並利用Industrial Source Complex (ISC)進行模式模擬，由於物種數量較多，彼此間的年平均增量濃度分布皆不盡相同，故將增量濃度換算為健康風險評估中的致癌風險值，並將各物種進行加總為總致癌風險值，藉此用來分析有害空氣污染物環境監測站最適位置。

中文關鍵字

有害空氣污染物、環境監測、監測網

類型	檔名	檔案大小	說明	最新版公開日期
期末報告	有害空氣污染物周界監測網規劃先期計畫.pdf	20MB		2020/9/8 上午 12:00:00

摘要	The contents of this study include to consolidation of ambient monitoring measures for hazardous air pollutants and environmental monitoring methods for 29 hazardous air pollutants, photochemical assessment monitoring stations and field sampling data were analyzed the concentration characteristics of hazardous air pollutants in Taiwan and planning the location of environmental monitoring stations for hazardous air pollutants. It mainly collects the US Environmental Protection Agency's program specifications classified as air toxicants, which can be divided into National Air Toxic Trends Stations (NATTs), Urban Air Toxic Monitoring Program (UATMP), and Community Scale Air Toxics Ambient Monitoring (CSATAM).To collect different monitoring objectives, monitoring projects, monitoring station locations of HAPs ambient monitoring at other countries, including from the US Environmental Protection Agency (USEPA), European Air Pollutant Long-Range Transmission Monitoring and European Monitoring and Evaluation Programme (EMEP) and other countries as a reference for the planning of Taiwan's monitoring network. This study summarizes the monitoring methods for numbers of HAPs. The methods covers sampling and analysis methods for volatile organic compounds, mercury and other heavy metals. The median concentrations of benzene, toluene, ethylbenzene and xylene in the photochemical assessment monitoring stations have been declining year by year. In addition to the Siaogang, each station has the lowest value in 2018. Based on the data measured in special industrial zones from 2016 to 2018, the median concentratons of species monitored automatically showed a trend of decreasing year by year. In Kaohsiung, five fields were continuously sampled on-site at least seven days. The concentration characteristics of Taiwan's HAPs were analyzed and the comparison of VOCs and heavy metal samples was performed. The VOCs were sampled using the MiTAP automatic instrument and the stainless steel canisters manual method. The heavy metal automatic monitoring was performed by Xact 625i and the manual sampling used an open-face sampler. Formaldehyde and acetaldehyde used LpDNPH-Cartridge for chemical adsorption to collect samples; asbestos used three-piece filter paper, and PCBs used PUF high-sampler. The data showed that the highest average daily concentration of VOCs in each station was toluene and m,p-xylene, and the highest average daily concentration of heavy metals in each station was the lead. The project currently used PM and HC emissions data in TEDS10 from various sources to screen out the top 90% of the emission, and the Speciate-4.5 database to screen out the industry codes, vehicle codes and the source code separately found the corresponding fingerprint data for subsequent emission estimation. The estimated emissions of various industries divided into counties and cities, and used Industrial Source Complex (ISC) doing model simulation. Due to the large number of species, the annual average incremental concentration distribution is different. Therefore, the incremental concentration is converted into the cancer risk value in the health risk assessment, and the species are aggregated into the total cancer risk value, which is used to analyze the optimal position of the environmental monitoring station for hazardous air pollutants.
英文關鍵字	Hazardous Air Pollutants, Environmental Monitoring, Air Monitoring Network

摘要

The contents of this study include to consolidation of ambient monitoring measures for hazardous air pollutants and environmental monitoring methods for 29 hazardous air pollutants, photochemical assessment monitoring stations and field sampling data were analyzed the concentration characteristics of hazardous air pollutants in Taiwan and planning the location of environmental monitoring stations for hazardous air pollutants. It mainly collects the US Environmental Protection Agency's program specifications classified as air toxicants, which can be divided into National Air Toxic Trends Stations (NATTs), Urban Air Toxic Monitoring Program (UATMP), and Community Scale Air Toxics Ambient Monitoring (CSATAM).To collect different monitoring objectives, monitoring projects, monitoring station locations of HAPs ambient monitoring at other countries, including from the US Environmental Protection Agency (USEPA), European Air Pollutant Long-Range Transmission Monitoring and European Monitoring and Evaluation Programme (EMEP) and other countries as a reference for the planning of Taiwan's monitoring network. This study summarizes the monitoring methods for numbers of HAPs. The methods covers sampling and analysis methods for volatile organic compounds, mercury and other heavy metals. The median concentrations of benzene, toluene, ethylbenzene and xylene in the photochemical assessment monitoring stations have been declining year by year. In addition to the Siaogang, each station has the lowest value in 2018. Based on the data measured in special industrial zones from 2016 to 2018, the median concentratons of species monitored automatically showed a trend of decreasing year by year. In Kaohsiung, five fields were continuously sampled on-site at least seven days. The concentration characteristics of Taiwan's HAPs were analyzed and the comparison of VOCs and heavy metal samples was performed. The VOCs were sampled using the MiTAP automatic instrument and the stainless steel canisters manual method. The heavy metal automatic monitoring was performed by Xact 625i and the manual sampling used an open-face sampler. Formaldehyde and acetaldehyde used LpDNPH-Cartridge for chemical adsorption to collect samples; asbestos used three-piece filter paper, and PCBs used PUF high-sampler. The data showed that the highest average daily concentration of VOCs in each station was toluene and m,p-xylene, and the highest average daily concentration of heavy metals in each station was the lead. The project currently used PM and HC emissions data in TEDS10 from various sources to screen out the top 90% of the emission, and the Speciate-4.5 database to screen out the industry codes, vehicle codes and the source code separately found the corresponding fingerprint data for subsequent emission estimation. The estimated emissions of various industries divided into counties and cities, and used Industrial Source Complex (ISC) doing model simulation. Due to the large number of species, the annual average incremental concentration distribution is different. Therefore, the incremental concentration is converted into the cancer risk value in the health risk assessment, and the species are aggregated into the total cancer risk value, which is used to analyze the optimal position of the environmental monitoring station for hazardous air pollutants.

英文關鍵字

Hazardous Air Pollutants, Environmental Monitoring, Air Monitoring Network