環保專案成果報告查詢系統

專案計畫編號	YLEPB-111-014
經費年度	111
計畫經費	6,710 千元
預算科目	地方政府執行空氣污染防制工作
專案開始日期	2022/02/09
專案結束日期	2022/12/31
專案主持人	張文旭
主辦單位	雲林縣環境保護局
承辦人	曾鴻智
執行單位	金煇企業股份有限公司
專案分類	大氣空氣、環境監測及檢測
中文關鍵字	石化業、異味、揮發性有機物
英文關鍵字	petrochemical industry, odor, volatile organic compounds (VOCs)
協同主持人
共同主持人
計畫聯絡人	張文旭
計畫聯絡電話	04-23167148#500
計畫聯絡信箱	zupa@leder.com.tw

中文摘要	石化業排放烷類、烯類、苯環類……等VOCs物質，對健康有不利的影響，兩輛石化業專用監測車是針對六輕石化工業區排放特徵設置，監測項目包括基準污染物、VOCs、還原硫及氨。本計畫目標在維持石化業專用監測車及監測設備正常運轉，透過定期保養與品保品管（QA／QC）作業，確保監測設備準確度及監測數據品質，並透過數據分析，瞭解六輕工業區周界及陳情熱點之空氣品質狀況，作為本縣改善空氣品質及制訂管制策略之參考。兩輛監測車監測設備之層級維護與品保作業均依時程執行，各月之單機資料獲取率在 80 %以上。許厝分校是六輕石化工業區周界的長期監測點，111/01/01 至 111/12/31 監測期間，基準污染物O3, 8hr和PM2.5超標，超標日數分別為 54 天/及 1 天。異味物種H2S與NH3超過嗅覺閾值，超過比例為 15.1 %與 0.9 %。揮發性有機物監測顯示，烷類占 44.1 %為最高，次為烯類占 25.1 %，物種中以乙烯平均濃度 1.71 ppbv最高。近年斗南異味陳情問題頻傳，今年局端指示調配一輛石化業專用監測車支援監測，義和聖母宮及斗南田徑場屬於異味陳情監測點。義和聖母宮 111/02/26 至 111/05/26、111/09/22 至 111/10/06 監測期間，基準污染物O3, 8hr和PM2.5超標，超標日數分別為 9 天及 12 天。異味物種H2S、DMS、Methyl-SH及NH3超過嗅覺閾值，H2S超過比例為 48.5 %，其次為NH3的 11.8 %。揮發性有機物監測顯示，烷類比例占 48.0 %最高，次為芳香烴類占 33.1 %。物種中以甲苯平均濃度 3.60 ppbv最高。斗南田徑場 111/05/26 至 111/09/22、111/10/06 至 111/12/31 監測期間，基準污染物O3, 8hr超標，超標日數為 12 天。異味物種H2S、DMS及NH3超過嗅覺閾值，H2S超過比例為 58.6 %，其次為DMS的 10.3 %。揮發性有機物監測顯示，芳香烴類占 47.1 %為最高、次為烷類占 37.3 %。物種中以甲苯平均濃度 5.26 ppbv最高。
中文關鍵字	石化業、異味、揮發性有機物

中文摘要

石化業排放烷類、烯類、苯環類……等VOCs物質，對健康有不利的影響，兩輛石化業專用監測車是針對六輕石化工業區排放特徵設置，監測項目包括基準污染物、VOCs、還原硫及氨。本計畫目標在維持石化業專用監測車及監測設備正常運轉，透過定期保養與品保品管（QA／QC）作業，確保監測設備準確度及監測數據品質，並透過數據分析，瞭解六輕工業區周界及陳情熱點之空氣品質狀況，作為本縣改善空氣品質及制訂管制策略之參考。兩輛監測車監測設備之層級維護與品保作業均依時程執行，各月之單機資料獲取率在 80 %以上。許厝分校是六輕石化工業區周界的長期監測點，111/01/01 至 111/12/31 監測期間，基準污染物O3, 8hr和PM2.5超標，超標日數分別為 54 天/及 1 天。異味物種H2S與NH3超過嗅覺閾值，超過比例為 15.1 %與 0.9 %。揮發性有機物監測顯示，烷類占 44.1 %為最高，次為烯類占 25.1 %，物種中以乙烯平均濃度 1.71 ppbv最高。近年斗南異味陳情問題頻傳，今年局端指示調配一輛石化業專用監測車支援監測，義和聖母宮及斗南田徑場屬於異味陳情監測點。義和聖母宮 111/02/26 至 111/05/26、111/09/22 至 111/10/06 監測期間，基準污染物O3, 8hr和PM2.5超標，超標日數分別為 9 天及 12 天。異味物種H2S、DMS、Methyl-SH及NH3超過嗅覺閾值，H2S超過比例為 48.5 %，其次為NH3的 11.8 %。揮發性有機物監測顯示，烷類比例占 48.0 %最高，次為芳香烴類占 33.1 %。物種中以甲苯平均濃度 3.60 ppbv最高。斗南田徑場 111/05/26 至 111/09/22、111/10/06 至 111/12/31 監測期間，基準污染物O3, 8hr超標，超標日數為 12 天。異味物種H2S、DMS及NH3超過嗅覺閾值，H2S超過比例為 58.6 %，其次為DMS的 10.3 %。揮發性有機物監測顯示，芳香烴類占 47.1 %為最高、次為烷類占 37.3 %。物種中以甲苯平均濃度 5.26 ppbv最高。

中文關鍵字

石化業、異味、揮發性有機物

類型	檔名	檔案大小	說明	最新版公開日期
期末報告	111年度雲林縣石化業專用監測車操作維護計畫-期末報告定稿.pdf	13MB	111年度雲林縣石化業專用監測車操作維護計畫-期末報告定稿	2024/3/6 上午 12:00:00

摘要	The petrochemical industry emits alkanes, alkenes, benzene rings, and other VOCs, which are hazardous to human health. The two monitoring vehicles for the petrochemical industry are set up for the emission characteristics of The No. 6 Naphtha Cracker Complex, and the monitoring species include criteria pollutants, VOCs, H2S, and NH3. This project aims to maintain the regular operation of vehicles and equipment dedicated to air quality monitoring for the petrochemical industry. This goal is achieved through routine maintenance and QA/QC to ensure the accuracy of monitoring equipment and data quality. The second goal of this project is to understand the impacts of The No. 6 Naphtha Cracker Complex on regional air quality through data analysis. This information can be incorporated into policymaking strategies at the county level to improve air quality. Maintenance and quality assurance were performed on monitoring equipment at all levels according to a predetermined schedule. The usability of monthly data from each device was over 80%. The Ciaotou Elementary School, Xucuo Campus is a long-term monitoring point for the perimeter of The No. 6 Naphtha Cracker Complex. In terms of the criteria pollutant, the levels of O3, 8hr and PM2.5 exceeded the standard at the Ciaotou Elementary School, Xucuo Campus from January through December 2022. And the exceeded days were 54 days and 1 day, respectively. Among the odor pollutants measured at this site, the levels of H2S and NH3 exceeded the olfactory threshold, ratios were 15.1 % and 0.9 %. The results of volatile organic compounds (VOCs) shows that alkanes accounted for 44.1 % of the total, followed by alkenes accounted for 25.1 %. Among the species, the highest level of average concentration was ethylene, at 1.71 ppbv. In recent years, the problem of odor in Dounan Township has been frequently reported. This year, the EPB instructed to deploy a monitoring vehicle for the petrochemical industry to the Yihe Shengmu Temple and the Dounan Municipal Stadium for monitoring. The two points are monitoring for odor reported. In terms of the criteria pollutant, the levels of O3, 8hr and PM2.5 exceeded the standard at the Yihe Shengmu Temple from February 26 through May 26 and September 22 through October 6 2022. And the exceeded days were 9 days and 12 days, respectively. Among the odor pollutants measured at this site, the levels of H2S, DMS, Methyl-SH and NH3 exceeded the olfactory threshold. And the highest ratio was H2S, at 48.5 %, followed by NH3 accounted for 11.8 %. The results of VOCs show that alkanes accounted for 48.0 % of the total, followed by aromatics accounted for 33.1 %. Among the species, the highest level of average concentration was toluene, at 3.60 ppbv. In terms of the criteria pollutant, the levels of O3, 8hr exceeded the standard at the Dounan Municipal Stadium from May 26 through September 22 and Octember 6 through December 31 2022. And the exceeded days were 12 days. Among the odor pollutants measured at this site, the levels of H2S, DMS and NH3 exceeded the olfactory threshold. And the highest ratio was H2S, at 58.6 %, followed by DMS accounted for 10.3 %. The results of VOCs show that aromatics accounted for 47.1 % of the total, followed by alkanes accounted for 37.3 %. Among the species, the highest level of average concentration was toluene, at 5.26 ppbv.
英文關鍵字	petrochemical industry, odor, volatile organic compounds (VOCs)

摘要

The petrochemical industry emits alkanes, alkenes, benzene rings, and other VOCs, which are hazardous to human health. The two monitoring vehicles for the petrochemical industry are set up for the emission characteristics of The No. 6 Naphtha Cracker Complex, and the monitoring species include criteria pollutants, VOCs, H2S, and NH3. This project aims to maintain the regular operation of vehicles and equipment dedicated to air quality monitoring for the petrochemical industry. This goal is achieved through routine maintenance and QA/QC to ensure the accuracy of monitoring equipment and data quality. The second goal of this project is to understand the impacts of The No. 6 Naphtha Cracker Complex on regional air quality through data analysis. This information can be incorporated into policymaking strategies at the county level to improve air quality. Maintenance and quality assurance were performed on monitoring equipment at all levels according to a predetermined schedule. The usability of monthly data from each device was over 80%. The Ciaotou Elementary School, Xucuo Campus is a long-term monitoring point for the perimeter of The No. 6 Naphtha Cracker Complex. In terms of the criteria pollutant, the levels of O3, 8hr and PM2.5 exceeded the standard at the Ciaotou Elementary School, Xucuo Campus from January through December 2022. And the exceeded days were 54 days and 1 day, respectively. Among the odor pollutants measured at this site, the levels of H2S and NH3 exceeded the olfactory threshold, ratios were 15.1 % and 0.9 %. The results of volatile organic compounds (VOCs) shows that alkanes accounted for 44.1 % of the total, followed by alkenes accounted for 25.1 %. Among the species, the highest level of average concentration was ethylene, at 1.71 ppbv. In recent years, the problem of odor in Dounan Township has been frequently reported. This year, the EPB instructed to deploy a monitoring vehicle for the petrochemical industry to the Yihe Shengmu Temple and the Dounan Municipal Stadium for monitoring. The two points are monitoring for odor reported. In terms of the criteria pollutant, the levels of O3, 8hr and PM2.5 exceeded the standard at the Yihe Shengmu Temple from February 26 through May 26 and September 22 through October 6 2022. And the exceeded days were 9 days and 12 days, respectively. Among the odor pollutants measured at this site, the levels of H2S, DMS, Methyl-SH and NH3 exceeded the olfactory threshold. And the highest ratio was H2S, at 48.5 %, followed by NH3 accounted for 11.8 %. The results of VOCs show that alkanes accounted for 48.0 % of the total, followed by aromatics accounted for 33.1 %. Among the species, the highest level of average concentration was toluene, at 3.60 ppbv. In terms of the criteria pollutant, the levels of O3, 8hr exceeded the standard at the Dounan Municipal Stadium from May 26 through September 22 and Octember 6 through December 31 2022. And the exceeded days were 12 days. Among the odor pollutants measured at this site, the levels of H2S, DMS and NH3 exceeded the olfactory threshold. And the highest ratio was H2S, at 58.6 %, followed by DMS accounted for 10.3 %. The results of VOCs show that aromatics accounted for 47.1 % of the total, followed by alkanes accounted for 37.3 %. Among the species, the highest level of average concentration was toluene, at 5.26 ppbv.

英文關鍵字

petrochemical industry, odor, volatile organic compounds (VOCs)