環保專案成果報告查詢系統

專案計畫編號
經費年度	113
計畫經費	14,620 千元
預算科目	評估管理-評估管理
專案開始日期	2024/01/12
專案結束日期	2024/11/30
專案主持人	簡瀅珊
主辦單位	化學署評估管理組
承辦人	王郁芬
執行單位	環化有限公司
專案分類	化學物質管理
中文關鍵字	毒性及關注化學物質、後市場、採樣檢測、網路查核、邊境管理
英文關鍵字	Toxic and concerned chemical substances, Post-market,Sampling and testing, E-commerce inspections, Border management
協同主持人	陳孟筠
共同主持人
計畫聯絡人	簡瀅珊
計畫聯絡電話	02-23142030#301
計畫聯絡信箱	ru013@echem.tw

中文摘要	計畫工作重點包含化學物質稽查及輔導訪查、推動邊境管理、特定化學物質及市售產品抽測、強化快篩技術應用及落實查核毒性及關注化學物質非法網路交易，工作成果說明如下：化學物質稽查及輔導訪查：分為2種對象執行稽查及輔導訪查作業，專案稽查已列管業者為主，主要稽查樣態為勾稽異常上下游輸入流向異常，共執行7家次，其中4家勾稽異常業者皆於改善期限內完成改善；非列管業者以輔導訪查方式執行37家次，總計已於11月10日完成44家次2種對象及7種樣態資料彙整。同時協助跨部會合作化學品聯合稽查作業1,727家查檢成果彙整，追蹤433家缺失改善情形。推動邊境管理：進行邊境查驗、特定化學物質稽查及市售商品採樣分析，本年度完成15場次採樣作業，其中7場次為邊境查驗完成4個樣品檢測、8場次為特定化學物質輔訪完成57件樣品檢測、協助地方政府執行列管化學物質查緝笑氣樣品139件（均有檢出笑氣）、壬基酚1件，總計檢驗201件樣品。另為提升相關人員的專業技能，於113年8月21日辦理2場次稽查及採樣檢測教育訓練。網路販售列管化學物質及市售產品抽測：查核毒性及關注化學物質非法網路交易共58,981筆風險名單，輔導51件商品下架，彙整地方環保局完成違規裁處5案。市售產品抽測完成30件商品檢驗，包括家用清潔劑、兒童玩具、文具用品、表面處理劑和瑜珈墊，檢驗物質分為壬基酚、壬基酚聚乙氧基醇、氫氟酸等12種毒性及關注化學物質，結果均符合相關規範及低於管制濃度。強化快篩技術應用：完成國內外得克隆、甲氧滴滴涕及UV-328共計3種物質檢測方法資料蒐集，建議未來UV-328與得克隆可採用氣相層析質譜儀分析檢測，而甲氧滴滴涕建議未來檢測方法則可以氣相層析質譜儀及電子捕捉偵測器。另針對手持式拉曼光譜儀可識別濃度範圍分別為壬基酚15%、壬基酚聚氧乙基醇10%、甲基異丁酮90%、二甲基甲醯胺60%及二氯甲烷60%，但儀器在高濃度或複雜混合物情境中仍存在限制；於水環境生態毒理完成2個物質測試，五乙烯六胺水環境生態毒理，其活性污泥的呼吸率抑制試驗結果為EC50=428 mg/L；28天生物降解度試驗結果為7%，而亞磷酸三壬苯酯之活性污泥的呼吸率抑制試驗結果為EC50大於10,000 mg/L；28 天生物降解度試驗結果為 6%，為物質本身具不易快速生物降解之特性。行政管理作業完成協助化學物質查扣運送7趟次，提供150車次車輛租賃，彙整並製作稽查與輔導訪查工作影像紀錄。
中文關鍵字	毒性及關注化學物質、後市場、採樣檢測、網路查核、邊境管理

中文摘要

計畫工作重點包含化學物質稽查及輔導訪查、推動邊境管理、特定化學物質及市售產品抽測、強化快篩技術應用及落實查核毒性及關注化學物質非法網路交易，工作成果說明如下：化學物質稽查及輔導訪查：分為2種對象執行稽查及輔導訪查作業，專案稽查已列管業者為主，主要稽查樣態為勾稽異常上下游輸入流向異常，共執行7家次，其中4家勾稽異常業者皆於改善期限內完成改善；非列管業者以輔導訪查方式執行37家次，總計已於11月10日完成44家次2種對象及7種樣態資料彙整。同時協助跨部會合作化學品聯合稽查作業1,727家查檢成果彙整，追蹤433家缺失改善情形。推動邊境管理：進行邊境查驗、特定化學物質稽查及市售商品採樣分析，本年度完成15場次採樣作業，其中7場次為邊境查驗完成4個樣品檢測、8場次為特定化學物質輔訪完成57件樣品檢測、協助地方政府執行列管化學物質查緝笑氣樣品139件（均有檢出笑氣）、壬基酚1件，總計檢驗201件樣品。另為提升相關人員的專業技能，於113年8月21日辦理2場次稽查及採樣檢測教育訓練。網路販售列管化學物質及市售產品抽測：查核毒性及關注化學物質非法網路交易共58,981筆風險名單，輔導51件商品下架，彙整地方環保局完成違規裁處5案。市售產品抽測完成30件商品檢驗，包括家用清潔劑、兒童玩具、文具用品、表面處理劑和瑜珈墊，檢驗物質分為壬基酚、壬基酚聚乙氧基醇、氫氟酸等12種毒性及關注化學物質，結果均符合相關規範及低於管制濃度。強化快篩技術應用：完成國內外得克隆、甲氧滴滴涕及UV-328共計3種物質檢測方法資料蒐集，建議未來UV-328與得克隆可採用氣相層析質譜儀分析檢測，而甲氧滴滴涕建議未來檢測方法則可以氣相層析質譜儀及電子捕捉偵測器。另針對手持式拉曼光譜儀可識別濃度範圍分別為壬基酚15%、壬基酚聚氧乙基醇10%、甲基異丁酮90%、二甲基甲醯胺60%及二氯甲烷60%，但儀器在高濃度或複雜混合物情境中仍存在限制；於水環境生態毒理完成2個物質測試，五乙烯六胺水環境生態毒理，其活性污泥的呼吸率抑制試驗結果為EC50=428 mg/L；28天生物降解度試驗結果為7%，而亞磷酸三壬苯酯之活性污泥的呼吸率抑制試驗結果為EC50大於10,000 mg/L；28 天生物降解度試驗結果為 6%，為物質本身具不易快速生物降解之特性。行政管理作業完成協助化學物質查扣運送7趟次，提供150車次車輛租賃，彙整並製作稽查與輔導訪查工作影像紀錄。

中文關鍵字

毒性及關注化學物質、後市場、採樣檢測、網路查核、邊境管理

類型	檔名	檔案大小	說明	最新版公開日期
期末報告	113年化學物質調查與採樣檢測計畫專案倉儲上傳.pdf	15MB	成果報告	2025/1/15 上午 12:00:00

摘要	The project focuses on enhancing safety and compliance through key initiatives, including chemical substance inspections, advisory visits, the promotion of border management, sampling and testing of specific chemical substances and commercial products, strengthening the application of rapid screening technologies, and implementing e-commerce inspections of toxic chemical substances (TCSs) and concerned chemical substances (CCSs). The outcomes of these efforts are detailed as follows: The Chemical Substance Inspection and Guidance Visits have been conducted for two categories of entities, with a primary focus on operators under regulatory supervision. These inspections primarily addressed irregularities, including discrepancies between input and output in both upstream and downstream processes. In the case of regulated operators, seven special inspections were conducted, where four operators recognized inconsistencies and effectively implemented corrective actions within the designated period. For non-regulated operators, 37 guidance visits were carried out. As of November 10, data collection for both groups and seven distinct categories has been finalized, resulting in a total of 44 special inspections. Additionally, we have supported interagency collaboration on joint chemical inspections, compiling results from 1,727 inspections and following up on corrective actions for 433 businesses with identified issues. For promoting border management, we conducted border inspections, specific chemical substance checks, and sampling analysis of commercial products, completing a total of 15 rounds of sampling and testing. We dedicated seven rounds to border inspections, which resulted in four samples being tested; eight rounds were aimed at advisory visits concerning specific chemical substances, resulting in 57 samples tested. We also assisted local governments in implementing regulations on controlled chemicals, which included testing 139 nitrous oxide (N2O) samples (with all returning positive for N2O) and 1 sample of nonylphenol, total of 201 samples. Additionally, to improve the professional skills of relevant personnel, two training sessions focused on inspection, sampling, and testing were held on August 21, 2024. In the e-commerce inspections of toxic chemical substances (TCSs) and concerned chemical substances (CCSs), we reviewed 58,981 high-risk products. This resulted in the removal of 51 products and issuance of 5 determinations by the Environmental Protection Bureau. Furthermore, we conducted testing on 30 products, including household cleaners, children's toys, stationery, surface treatment agents, and yoga mats, with no detection of 12 targeted toxic and concerned chemical substances such as nonylphenol, nonylphenol ethoxylates, and hydrofluoric acid. As for strengthening rapid screening technology applications, we have completed the collection of domestic and international testing methods for dechlorane, methoxychlor DDT, and UV-328. UV-328 and dechlorane are primarily analyzed using gas chromatography-mass spectrometry (GC-MS), while methoxychlor DDT is tested using GC-MS and electron capture detector. Additionally, we conducted handheld Raman spectrometry device detection tests were 15% for nonylphenol, 10% for nonylphenol polyethylene glycol ether, 90% for methyl isobutyl ketone, 60% for N,N-Dimethyl formamide, and 60% for Dichloromethane respectively. However, the instrument still has limitations in high-concentration or complex mixture scenarios. The aquatic ecotoxicology tests for two substances have been completed. An eco-toxicity assessment of pentaethylenehexamine in aquatic environments indicated an EC50 of 428 mg/L, with a 28-day biodegradability test result of 7%. For tris(nonylphenyl) phosphite, the activated sludge respiration inhibition test showed an EC50 greater than 10,000 mg/L, with a 28-day biodegradability result of 6%, suggesting a low potential for rapid biodegradation. Administrative tasks included assisting transport of confiscated chemical substances 7 times, arranging 150 vehicle rentals, and creating video records of inspections and advisory visits.
英文關鍵字	Toxic and concerned chemical substances, Post-market,Sampling and testing, E-commerce inspections, Border management

摘要

The project focuses on enhancing safety and compliance through key initiatives, including chemical substance inspections, advisory visits, the promotion of border management, sampling and testing of specific chemical substances and commercial products, strengthening the application of rapid screening technologies, and implementing e-commerce inspections of toxic chemical substances (TCSs) and concerned chemical substances (CCSs). The outcomes of these efforts are detailed as follows: The Chemical Substance Inspection and Guidance Visits have been conducted for two categories of entities, with a primary focus on operators under regulatory supervision. These inspections primarily addressed irregularities, including discrepancies between input and output in both upstream and downstream processes. In the case of regulated operators, seven special inspections were conducted, where four operators recognized inconsistencies and effectively implemented corrective actions within the designated period. For non-regulated operators, 37 guidance visits were carried out. As of November 10, data collection for both groups and seven distinct categories has been finalized, resulting in a total of 44 special inspections. Additionally, we have supported interagency collaboration on joint chemical inspections, compiling results from 1,727 inspections and following up on corrective actions for 433 businesses with identified issues. For promoting border management, we conducted border inspections, specific chemical substance checks, and sampling analysis of commercial products, completing a total of 15 rounds of sampling and testing. We dedicated seven rounds to border inspections, which resulted in four samples being tested; eight rounds were aimed at advisory visits concerning specific chemical substances, resulting in 57 samples tested. We also assisted local governments in implementing regulations on controlled chemicals, which included testing 139 nitrous oxide (N2O) samples (with all returning positive for N2O) and 1 sample of nonylphenol, total of 201 samples. Additionally, to improve the professional skills of relevant personnel, two training sessions focused on inspection, sampling, and testing were held on August 21, 2024. In the e-commerce inspections of toxic chemical substances (TCSs) and concerned chemical substances (CCSs), we reviewed 58,981 high-risk products. This resulted in the removal of 51 products and issuance of 5 determinations by the Environmental Protection Bureau. Furthermore, we conducted testing on 30 products, including household cleaners, children's toys, stationery, surface treatment agents, and yoga mats, with no detection of 12 targeted toxic and concerned chemical substances such as nonylphenol, nonylphenol ethoxylates, and hydrofluoric acid. As for strengthening rapid screening technology applications, we have completed the collection of domestic and international testing methods for dechlorane, methoxychlor DDT, and UV-328. UV-328 and dechlorane are primarily analyzed using gas chromatography-mass spectrometry (GC-MS), while methoxychlor DDT is tested using GC-MS and electron capture detector. Additionally, we conducted handheld Raman spectrometry device detection tests were 15% for nonylphenol, 10% for nonylphenol polyethylene glycol ether, 90% for methyl isobutyl ketone, 60% for N,N-Dimethyl formamide, and 60% for Dichloromethane respectively. However, the instrument still has limitations in high-concentration or complex mixture scenarios. The aquatic ecotoxicology tests for two substances have been completed. An eco-toxicity assessment of pentaethylenehexamine in aquatic environments indicated an EC50 of 428 mg/L, with a 28-day biodegradability test result of 7%. For tris(nonylphenyl) phosphite, the activated sludge respiration inhibition test showed an EC50 greater than 10,000 mg/L, with a 28-day biodegradability result of 6%, suggesting a low potential for rapid biodegradation. Administrative tasks included assisting transport of confiscated chemical substances 7 times, arranging 150 vehicle rentals, and creating video records of inspections and advisory visits.

英文關鍵字

Toxic and concerned chemical substances, Post-market,Sampling and testing, E-commerce inspections, Border management