環境資源報告成果查詢系統

利用堆肥液以提高生物溶解與降解四氯乙烯之研究

中文摘要 四氯乙烯為主要常見的為地下水污染物之一,由於其密度高且非水溶相之特性,使其不易利用傳統的物化處理方法,將其從地下水中移除。本計畫嘗試利用廉價的堆肥液來取代商用的生物製劑,以評估堆肥液能否作為適當的界面活性劑與電子提供者,以加速四氯乙烯在地下水層中的溶解與生物降解。本計畫共測試三種不同的堆肥:三個月蔗渣堆肥(B3)、六個月蔗渣堆肥(B6),與三個月蔗渣/廚餘混合堆肥(M3)之介面活性性質,以評估不同堆肥液對四氯乙烯的溶解效率,並利用B3堆肥進行管柱實驗,評估不同堆肥量對四氯乙烯的移除效率。實驗結果顯示,腐熟度低的堆肥,其介面活性性質較腐熟度高的堆肥為佳,而加入廚餘於蔗渣堆肥中更可提升其介面活性劑之性質。管柱實驗結果則顯示,相較於蔗渣原料,蔗渣堆肥能更有效的將下游的四氯乙烯溶出,且溶出效率隨著堆肥量的增加而提高。在近180天的培育時間過程中,堆肥能持續的維持系統中的甲烷產量,而能有效的降解四氯乙烯,同時能維持系統中近於中性的pH值。綜而言之,由於堆肥具有適度的介面活性性質以及多樣的微生物活性,使得堆肥可作為一種整治土壤地下水四氯乙烯污染的良好資材。
中文關鍵字 堆肥、還原脫氯、管柱實驗

基本資訊

專案計畫編號 EPA-99-GA103-03-A23 經費年度 099 計畫經費 990 千元
專案開始日期 2010/12/29 專案結束日期 2011/12/28 專案主持人 崔砢
主辦單位 土污基管會 承辦人 尤衍翔 執行單位 明志科技大學

成果下載

類型 檔名 檔案大小 說明
期末報告 期末報告(修正版2).pdf 2MB

Biologically Enhanced Dissolution and Transformation of Tetrachloroethene by Compost Liquid

英文摘要 Tetrachloroethene (PCE) is one of most found groundwater pollutants. Because it was denser than water and it would not mix with water easily, PCE was difficult to be removed from groundwater through traditional physical-chemical methods. Therefore, compost liquid was proposed as cheap alternative to commercial biological agents to improve the solubility and biodegradation of PCE. In this study, three compost samples: 3-month bagasse compost sample (B3), 6-month bagasse compost sample (B6), and 3-month bagasse compost/ kitchen waste mixed sample (M3) were examined for their biosurfactant property. In addition, B3 sample was selected to conduct column study to evaluate the effects of compost mass on the PCE remove efficiency. The experimental results showed that less matured sample had better biosurfactant property than more matured sample, and addition of kitchen waste would further enhance biosurfactant property. The results of column study showed that bagasse compost could dissolve more down-stream PCE when compared with bagasse sample, and the efficiency increased with increasing of compost mass. During 180 days of column study, sustainable amount of methane gas was detected in system, suggesting compost could be used as long-term electron donors to degrade PCE. The system remained at neutral pH throughout the experiment. Overall, compost contains moderate biosurfancant property and diverse microbial activity, and thus could serve as suitable media for dechlorinating groundwater PCE.
英文關鍵字 compost, reductive dechlorination, column study