英文摘要 |
The sludge from a variety of industries can be different due to manufacture process, materials used, chemical reagent, wastewater treatment facility, and operations. However, if the same industry using similar process and other similarities may not be able to tell the difference in sludge by using common analytical methods such as ICP/AES, ICP/MS, GC/MS, and LC/MS/MS. Thus, optical analyses like microscopy, SEM, TEM, and XRD would help observe the surface of the sludge such as appearance, crystalline, and molecular structure for difference.
This project was to study the finger-printing forensic technology in various industries’ sludge and collect the forensic features of the sludge from industries such as printed circuit boards (PCB), calcium fluorite, leather industries, TFT-LCD, food industries, pulp, and domestic wastewater treatment plants. This project also collected various forensic methods for sludge and applied it for establishing the forensic technology for this project.
With respect to the forensic technology and the finger-print features of the sludge of the LCD, LED, and DRAM industries, SEM was used to observe the appearance and featured constituents of the EDX. XRD was used to examine the crystalline and the related structure of the sludge coupled with XRF (or EDX) to determine the primary, secondary, and trace constituents. ICP was used to determine the concentrations of the metal elements and Headspace-GC/MS was used to analyze the organics for qualification and quantification. IC and LC/MS/MS were used to analyze the highly soluble chemicals such as TMAH, PFAAs, NPxEO, and OPxEO. Based on the results of using the above analytical methods, the industrial features of LED, DRAM, and LCD are studied and summarized as the follows:
1. Feature fingerprint of the LED industry:
XRD: SiO2、CaF2
Metals: As, Ga, In
2. Feature fingerprint of the DRAM industry:
XRD: SiO2, CaF2
Metals: Ce, W
Organics: EA, PGME, PGMEA, NMP, DMSO, BDG
3. Feature fingerprint of the LCD industry:
XRD: Si-C, Si
Metals: Ce, In, Sr, La
Organics: EA, PGME, PGMEA, NMP, DMSO, BDG, TMAH, NPxEO&OPxEO
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