環境資源報告成果查詢系統

排放管道排氣熱值之量測技術開發研究

中文摘要 本計畫旨在建立排放管道中排氣熱值之量測技術,用以提供環保署環檢所標準作業之參考依據。 針對排放管道排氣熱值分析方法,經評估後使用ASTM D4891燃燒直測熱值方法進行技術開發。燃燒直測法將排放管道氣體導入燃燒腔體,氣體與燃料混合燃燒,測得火焰溫度變化經計算得排放熱值。燃燒直測法系統需1小時穩定間即可連續量測熱值,最重要的零點及全幅校需約 90 秒的時間讀值達到穩定(T90),總時間約需5分鐘。檢量線範圍由甲烷定之,可由甲烷濃度5%-100%所分析的熱值46-1012BTU/ft3,實測結果與理論值比對介於90.91-99.41%之間,誤差範圍小於10%。利用甲烷實驗結果,利用燃燒直測法建立熱值分析方法準確度100.03±1.35%,精密度0.68%。利用丙烷、氫氣和甲苯作為盲樣分析時,各物種的熱值理論值與實際值差異均可在誤差範圍20%以內。 7場次實測分析結果顯示,燃燒直測法所測得的總熱值與層析法連續監測的總熱值有不錯的正相關,相關係數最佳的兩場次達0.926-0.992。然而燃燒直測法熱值分析結果與THC分析連續量測結果大致上有相似的趨勢,但THC與熱值趨勢出現變化時,並非均出現一致的變化。 本研究開發的燃燒直測法已可分析排放管道如廢氣燃燒塔上游石化製程的熱值分析方法,對於中、下游石化製程的熱值分析需有更嚴謹的研究證據證明燃燒直測法適用於中下游石化業的熱值實測,建議可針對石化製程上、中、下游廢氣燃燒塔的成分進行檢測分析,並建立廢氣燃燒塔廢氣資料庫,比對熱值分析結果和成分分析結果在不同製程、不同成分廢氣燃燒塔的相關性。 基於本計畫的研究技術成果,可建議環檢所建立燃燒直測法應用於排放管道的熱值量測,提供石化工業產業標準檢測技術,作為環保署訂定標準作業草案之參考。
中文關鍵字 石化工業;排放管道採樣;熱值

基本資訊

專案計畫編號 EPA-101-1602-02-02 經費年度 101 計畫經費 2900 千元
專案開始日期 2012/03/20 專案結束日期 2012/12/31 專案主持人 王介亨
主辦單位 環檢所 承辦人 王振興 執行單位 工業技術研究院 綠能所

成果下載

類型 檔名 檔案大小 說明
期末報告 1.排放管道中排氣熱值之量測技術開發研究_期末報告_定稿(公開版).pdf 3MB

Development of Heating Value Measurement Technology in Stack

英文摘要 The purpose of this project is to develop the measurement technology of high heating value in stacks and provide reference of testing methods to Environmental Analysis Laboratory, EPA. Achievements in the implementation: development of direct measurement method for analyzing high heating value of flare emissions which can be more intuitive and high heating value is calculated directly and precisely. Emission gas from stacks is introduced into the analysis units and the gas is mixed with fuel. The measured changes in the flame temperature through a heat value was calculated. Boot to system stability takes 1 hours, zero and full-size correction takes about 90 seconds of time reading to stabilize (T90). Calibration curve from methane to be determined by the methane concentration of the heating value 46-1012 BTU/ft3, the measured results with the theoretical value compared between 90.91-99.41%, the error range is less than 10% of the analyzed. Propane, Hydrogen and Toluene with methane calibration curve analysis the theory value and the actual value can be found in the error range of less than 20%. The method to measure the accuracy of 100.03 ± 1.35%, the precision of 0.68%. Seven performances measured results show good positive correlation (R2 = 0.8572-0.9844) of the high heating value with continuous monitoring method and chromatography method. Continuous monitoring method and results analysis with THC monitoring results generally have the same trend. Implementation of the policy side, based on the research and technological achievements of this project, we proposed that this direct continuous monitoring method can be established in the monitoring of the high heating value in stacks. This project is completed within the schedule and to provide draft standard method.
英文關鍵字 PetrochemicalIndustrial;Stack Sampling;Heating Value