英文摘要 |
The purposes of the project were (1) to integrate environmental sampling, including technology information of collection, integration and analyses, to establish the draft of 「Technical Guidance of Environmental Forensic Sampling」; (2) to utilize the existing technologies of river sediment forensic sampling to build forensic technology for targeted contaminants; (3) to build indicator chemical information of industrial sludge to test for representation with statistical analyses; (4) and to compile the forensic operation handbook.
The draft of 「Technical Guidance of Environmental Forensic Sampling」consisted of the information of environmental sampling and quality control from the US, the EU, and Australia to compile the guidebook of 「Quality Control for Environmental Sampling」. With considering practical experience, information of waste sampling plan, planning considerations, and sampling considerations from various countries was incorporated to compile the drafts of Institution draft Sampling Methods for Industrial Waste Generators、Sampling Methods for Recycled Wastes draft and Sampling Methods for Unidentified Wastes draft. With respect to establishing forensics of river sediment on targeted contaminants, the information collection of river sediments, water pollution background information, and contamination investigation was done prior to sample collection, analyses, and data analyses. With respect to the establishment of the indicator information of industrial sludge, the data and information files were built for LED, LCD, DRAM, leathering, petrochemical, printed circuit board, passive electronic, solar energy, and fabrication between 2012 and 2015. With respect to the representation test, samples were taken from the industries of fabrication, dye manufacturing, and petrochemical for analyses and the results were compared with the existing data in the database. With respect to the handbook compilation, sample pretreatment procedures and forensic procedure flowchart were included in order to track the contamination source and develop new forensic technologies.
The draft of 「Technical Guidance of Environmental Forensic Sampling」 and 「Operational Handbook of Environmental Forensic Technology」 were compiled. The results of representation test showed the sludge of fabrication, dye manufacturing, and petrochemical was positively representable, and the representable indicators are as follows:
1.Dye manufacturing:
Ba, Sr, barium sulfate, 3,3'-Dichlorobenzidine, 2,2',5,5'-Tetrachlorobenzidine, 1,1'-Biphenyl, 2,4'-dichloro-, 1,1'-Biphenyl, 2,2',3,4-tetrachloro-, 1,1'-Biphenyl, 2,2',4,4',5-pentachloro-, 1,1'-Biphenyl, 2,3,3',4,5,6-hexachloro-(polychlorinated benzene), Dioxin isomers
2.Fabrication industry:
A(C2H4O)nB, A(C3H6O)nB, C20H23N3O (antibacterial agent), C20H41NO2
3.Petrochemical industry:
Phthalic Anhydride(PA)、Plasticizers :Benzoic Acid, Benzoic Acid,2-methyl-, Phthalic anhydride, Di-n-octyl phthalate, tri(2-Ethylhexyl)trimellitate (TOTM)
Oil sludge:2,3-dimethyl-Naphthalene, 2-methyl-Phenanthrene, 2-methyl-Anthracene, 2-methyl-Pyrene, o-Terphenyl, 1,4-dimethyl-Anthracene, 1-methyl-Chrysene (PAHs)
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