環境資源報告成果查詢系統

105年度戴奧辛及細懸浮微粒排放源輔導管理(含空氣污染物)暨支援環保案件調查計畫

中文摘要 本計畫完成之工作:(1)56家次戴奧辛排放源工廠運作法規符合度現場查核及建檔;(2)113件次戴奧辛排放源申報資料、檢測報告審查與建檔及30家次工廠稽查、定期、改善、操作許可申請等檢測現場監督;(3)21根次排放管道戴奧辛稽查檢測;(4)10根次重點行業管道PM2.5排放特性檢測;(5)蘆竹區海湖坑口工業區異味污染源查證及空氣污染物種資料建立;(6)2季戴奧辛污染源密集地區及環保署測站桃園農工共3處環境空氣戴奧辛濃度監測;(7)環保署空品測站-平鎮環境空氣PM2.5監測與數據解析;(8)先豐通訊、和群纖維、尚佳公司等污染源製程用原物料之成分,協助確認空污費繳交金額、大園區美科科技與大同染整公司、宇鴻科技公司等異味監測、水美工程公司排放管道重金屬排放特性調查、泰豐輪胎火災事件災後污染物流佈調查、環境大氣HAP濃度監測等28件次支援環境污染案件調查與檢測。 本計畫審查113件次桃園市境內列管之戴奧辛排放源所申報之檢測報告書、檢測計畫書及其他相關資料,執行30家次列管戴奧辛排放源之檢測現場監督工作,本計畫人員於採樣過程中監督及查核工廠進料量與污防設備操作必須符合法規及操證的規範。 本計畫現場查核共計清查56家次戴奧辛排放源,清查工作針對列管廠家之戴奧辛排放源的進料量、焚化設備操作、污染防制設備運轉狀況、採樣設施條件等進行確認,現場各項操作參數以自行準備之科學儀器進行查驗,避免污染源數值造假,有效管控各廠防制設備狀況,針對不符合法規之廠家,提供必要之協助並追蹤其改善的完整性。 執行21根次列管戴奧辛排放源稽查檢測工作,不符合排放標準者共3根次,為使用廢木屑或木材為燃料之鍋爐、銅二級冶煉(含銅污泥處理),環保局對不符法規廠家告發處分,接續要求限期改善,及改善完成後檢測必須符合排放標準。 桃園市105年戴奧辛排放量推估,列管污染源戴奧辛總排放量為4.098 g-TEQ/year,約占環保署推估之104年度全國戴奧辛年排放量(53.3 g-TEQ/year)之1/13。 完成兩季環境空氣戴奧辛檢測,採樣點為水美工程辦公大樓、觀音區樹林國小、桃園農工監測站,夏季3處採樣點之平均濃度0.026 pg TEQ/Nm3,範圍介於0.016~ 0.042 pg TEQ/Nm3;冬季3處採樣點之平均濃度0.087 pg TEQ/Nm3,範圍介於0.046~ 0.145 pg TEQ/Nm3,雖冬季測值各處測較夏季高2 ~ 3倍,但3處採樣點之監測值均低於日本周界空氣戴奧辛環境品質基準年平均值0.6 pg-TEQ/Nm3。 本計畫於海湖國小執行異味污染源查證測得較高濃度之氯乙烯(VCM),該物種由海湖國小東北方飄過來,經至固定污染源管理系統比對資料,發現大洋塑膠工業股份有限公司桃園廠M01製程-聚氯乙烯塑膠製造程序有使用氯乙烯作為原料,每年使用量約183461.76公噸,已針對該廠進行設備元件稽查,發現有元件洩漏與污水廠未加蓋,並針對違規事項進行告發並限期改善;丙酮及甲苯由海湖國小西南西方飄過來,經至固定污染源管理系統比對資料,發現力信化工股份有限公司製程-其他化學製品製造業有使用甲苯及丙酮作為原料,被告發處分未有效收集廠內之污染物,目前正改善中,後續監督確認兩廠之改善成效。 本計畫至今已針對燃氣鍋爐、焚化爐、燃油鍋爐等三種類型污染源進行PM2.5排放特性調查,其中燃油鍋爐又細分針對油品種類、有無防制設備進行調查,以FPM2.5與CPM2.5排放結果來看,燃氣鍋爐之排放濃度較低且較穩定,大部分樣品之排放濃度是以FPM為主;燃油鍋爐PM2.5排放調查工作,目前FPM之濃度為未有防制設備之重油鍋爐=有防制設備之重油鍋爐>柴油鍋爐,CPM之濃度為未有防制設備之重油鍋爐>有防制設備之重油鍋爐>柴油鍋爐,裝有防制設備之燃油鍋爐對於PM2.5仍有一定之去除能力。 本計畫於平鎮測站以哈佛採樣器手動採樣分析與在線式氣體與氣膠成分監測儀監測大氣中的PM2.5成分,由分析數據可知平鎮測站PM2.5主要成分組成是以NO3-、SO42-、NH4+、NH3、HCOOH、K、Na、Zn為主,且由關聯性分析圖可知PM2.5與NO3-、NH4+、SO42-、NOx、Pb、Na之關聯性較高,前述污染物由國內研究資料多為移動污染源所排放,故平鎮測站受到移動污染源之影響較大。 本計畫於中壢區泰豐輪胎火災事件災後亦協助分析環保署中壢與平鎮空品測站1月17日12點至23點之風速風向資料、民眾陳情與新聞資料,選擇3處敏感受體作為災後監測之採樣點,分別為文化國小、中壢國中及中原大學,而檢測結果周界空氣戴奧辛濃度落於0.027~0.041 pg I-TEQ/m3皆低於北部都會區(北北基桃及新竹)或六都近五年之戴奧辛監測濃度範圍,故評估本次泰豐火災事件於周界空氣戴奧辛濃度並無異常情形。
中文關鍵字 環境監測、戴奧辛、細懸浮微粒、揮發性有機物、排放係數

基本資訊

專案計畫編號 經費年度 105 計畫經費 12720 千元
專案開始日期 2016/04/26 專案結束日期 2017/04/25 專案主持人 杜敬民
主辦單位 桃園市政府環境保護局 承辦人 吳怡貞 執行單位 財團法人工業技術研究院

成果下載

類型 檔名 檔案大小 說明
期末報告 計畫成果報告摘要(詳細版).pdf 0MB

This project is management and assistance of dioxin and fine particle matter emission and supported the investigation of environmental pollution cases(2016)

英文摘要 The major accomplishments of this project were as follows: (1) A total of 56 field examinations were conducted to check whether the participating factories conform to regulations on dioxin emission; (2) A total of 113 declarations of dioxin emission sources were examined and filed. Moreover, field supervision was conducted on 30 factories for routine audits, improvements, and operation permit applications were filed; (3) A total of 21 dioxin emission stacks were inspected; (4) The PM2.5 contents of the emission stacks of 10 factories were assessed; (5) Odorous pollution sources were localized, and air pollution species data were established in Haihu Kengkou Industrial Park of Luzhu District; (6) 2 seasons of dioxin pollution source agglomeration area and Environmental Protection Administration Taoyuan Nonggong Observation Station monitored the ambient air dioxin concentration monitoring; (7) Environmental Protection Administration Air Quality Observation Station – Pingchen conducted the ambient air PM2.5 monitoring and data analysis; (8) The following environmental pollution cases were investigated: the raw material ingredients in the pollution source processing of BoardTek Electronics, Ho Chun Fiber, and Shang Chia Corp.; the amount of assisting and conforming air pollution to be paid; the odorous monitoring in American Science & Technology, Tai-Tong Dying & Finishing, and Yuhong Scientific Company of Dayuan District; the heavy metal emission performance survey of discharging pipe of Shuimei Engineering Company; after-calamity pollutant spread survey of fire accident of Federal Corporation ; and the ambient atmosphere HAP concentration monitoring, totally 28 cases supporting the environmental pollution survey and detection. We reviewed 113 inspection reports, inspection plans, and other related documents declared as dioxin emission sources listed in Taoyuan; we conducted field supervision and inspected 30 registered emission sources of dioxin. During sampling, we monitored and verified whether the feed rates of factories and the operation of pollution-prevention equipment conformed to the regulations and operation standards for the entire course. We conducted 56 on-site examinations this project (including re-examination). The feed rates of dioxin emission sources, operations of incineration facilities, operating conditions of pollution-prevention equipment, and conditions of sampling facilities were validated. The operating parameters were inspected by scientific instruments, to avoid the pollution source value counterfeit, and effectively control the preventive equipment status of each factory, We established databases according to the condition of conformity and provided necessary assistance to factories that failed to conform to regulations. Follow ups were conducted to ensure the completion of improvement measures. We inspected 21 registered emission sources of dioxin. Among these factories, three failed to conform to emission standards. They included the sawdust or timber fuel boiler and the second-level copper smelting (including copper-sludge processing). These factories were identified by EPB and were required to implement improvement measures within a specified time. After improvements, the inspected emission concentration should conform to the standards. The amount of dioxin emission in 2016 was estimated to be 4.098 g-TEQ. This amount is approximately 1/13 of the annual national dioxin emission estimated by the Environmental Protection Administration in 2015 (53.3 g-TEQ/year). We completed two seasons of ambient air dioxin detection, and the sampling points were Shuimei Engineering Office Building, Shulin Primary School of Guanyin District, and Taoyuan Nonggong observation station; in summer, the average concentration of 3 sampling points was 0.026 pg TEQ/Nm3, in the scope of 0.016~ 0.042 pg TEQ/Nm3; in winter, the average concentration of 3 sampling points was 0.087 pg TEQ/Nm3, in the scope of 0.046~ 0.145 pg TEQ/Nm3; although the tested value in winter was 2 ~ 3 times higher than in summer, the tested values in 3 sampling points were all lower than Japanese ambient air dioxin environmental quality criteria annual average value of 0.6 pg-TEQ/Nm3. The odorous pollution source verification in Haihu Primary School acquired higher concentration of vinyl chloride (VCM), which was from the northeast of Haihu Primary School; through comparing the data of stationary pollution source management system, we found Ocean Plastics Co., Ltd. Taoyuan Factory M01 processing – polyvinyl chloride plastics manufacturing process adopted VCM as the raw material, with the annual usage amount about 183461.76 tons, and we inspected the equipment of the factory and found there was the component leakage and the sewage plant without capping, and thus reported the violation items and required to improve within limited time; the acetone and methylbenzene were from the southwest of Haihu Primary School; through comparing the data of stationary pollution source management system, we found Li Shin Chemical Co., Ltd. processing – other chemical products manufacturing industry adopted the acetone and methylbenzene as the raw material, and issued punishment of not effectively collecting the pollutant; at present the two cases are under improvement, and we shall supervise and confirm the improvement effect continuously. We also investigated the PM2.5 emission features of three kinds of pollutant sources during processing. These sources were gas fired boilers, incinerator boilers, and oil burning boilers, in which the oil burning boilers are divided into the types of different oils and with or without preventive equipment. According to the emission result of FPM2.5 and CPM2.5, the emission concentration of gas fired boiler was relatively low and stable. The emission concentration of most samples was composed mainly of FPM; through the oil burning boilers PM2.5 emission survey, FPM concentration of heavy oil boiler without preventive equipment = heavy oil boiler with preventive equipment > diesel oil boiler, CPM concentration of heavy oil boiler without preventive equipment > heavy oil boiler with preventive equipment > diesel oil boiler, which shows the oil burning boiler with preventive equipment has certain removal capacity to PM2.5. We manually sampled and analyzed the PM2.5 ingredients in the air in Pingchen observation station by Harvard sampling instrument and online gas and aerosol ingredient monitor; from the data analysis, it is known that PM2.5 major ingredients in Pingchen observation station are NO3-, SO42-, NH4+, NH3, HCOOH, K, Na, and Zn, and from the relevance analysis chart it is known that PM2.5 has higher relevance with NO3-, NH4+, SO42-, NOx, Pb, and Na; the above pollutants are mainly discharged from mobile pollution sources according to the domestic research data, thus Pingchen observation station is mainly influenced by mobile pollution sources. We assisted to analyze the wind speed and direction data from 12 o’clock to 23 o’clock on January 17 in Jhongli and Pingchen observation station of Environmental Protection Administration, the public petition and news data after the fire accident of Federal Corporation of Jhongli District, and selected 3 sensitive receivers as the sampling point of after-calamity monitoring, respectively Culture Primary School, Jhongli Junior High School and Chung Yuan Christian University, and the test result was that the ambient air dioxin concentration was 0.027~0.041 pg I-TEQ/m3, which was close to the dioxin monitoring concentration scope of northern metropolitan district (New Taipei, Taipei, Keelung, Taoyuan and Hsinchu) or six cities in recent five years, thus we assess there is no abnormal condition in the dioxin concentration of ambient air after the fire accident of Federal.
英文關鍵字 environmental monitoring, dioxin, PM2.5, VOCs, emission factor