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大氣懸浮微粒對能見度影響之研究

中文摘要 粒狀污染物在都會區空氣品質相關議題中均扮演著相當重要的角色,大氣懸浮微粒除了會造成空氣品質的惡化之外,微粒粒徑在2.5 µm以下之細懸浮微粒容易沉積於上呼吸道中,對人體健康危害很大,加上本身的對太陽短波輻射具有強烈的光學效應,進而影響大氣能見度,隨著民眾慢慢重視覺上的感受和健康以及環境上的考量,能見度的好壞變成是人們評斷空氣品質最重要的依據。 根據國內環保署空氣品質監測網96年至106年測站PM2.5年平均濃度統計,指出高屏為全國PM2.5年平均濃度最高地區,其中又以高雄都會區過去10年之能見度觀測資料統計(2006年至2016年),平均能見度約為6.5公里,最低月平均能見度則為5.4公里,因此,本研究進行前金(市區)和橋頭(郊區)大氣懸浮微粒採樣,探討不同季節(春、夏、秋和冬季)之微粒濃度特性,粒徑分佈、微粒成份組成和大氣相對濕度與能見度之關聯性。 根據前金和橋頭測站四季採樣結果指出,秋冬擁有春夏較高微粒濃度,其中又以秋季最高,夏季最低,但在平均粒徑方面,秋季和夏季有較高平均粒徑,原因在於兩季擁有較高相對濕度(RH>80%)以致增加微粒粒徑。微粒消光係數主要貢獻來源為散光係數,並同樣以秋季消光係數最高,夏季最低,與濃度比較趨勢有一樣結果,其中表面積和體積濃度與消光係數之關聯性,前金和橋頭RSQr都有0.87以上。成份組成中由於硫酸銨和硫酸銨有較高濃度和百分比,增加了微粒散光特性以致與消光係數有較高相關性,其RSQr均有0.8左右。前金硫酸銨和硝酸銨影響微粒消光係數主要粒徑分佈為0.46 µm - 0.7 µm,橋頭則為0.3 µm - 0.45 µm,由於前金影響微粒消光係數粒徑範圍介於可見光區(0.4 µm - 0.7 µm),以致於前金比橋頭有較低的能見度。在理論計算方面,在粒徑0.7 µm時,會達到最高的消光效率。本研究物質(硫酸銨、硝酸銨、元素碳和有機碳)理論與儀器消光係數之關聯性,其RSQr值均有0.9以上,並以理論計算出微粒消光粒徑分佈,前金主要消光粒徑分佈為0.48 µm - 0.78 µm,橋頭則為0.32 µm - 0.42 µm,其分佈與採樣分析出來的硫酸銨和硝酸銨主要影響微粒消光粒徑分佈有接近的結果,其表示當分佈中如果硫酸銨和硝酸銨粒徑大多落在可見光區(0.4 µm - 0.7 µm)時,消光係數就會隨著硫酸銨和硝酸銨粒徑濃度的提升,導致能見度的下降。
中文關鍵字 消光係數、微粒濃度、粒徑分佈、水溶性陰陽離子

基本資訊

專案計畫編號 EPA-106-FA18-03-A182 經費年度 106 計畫經費 10235 千元
專案開始日期 2017/09/01 專案結束日期 2018/08/31 專案主持人 林文印
主辦單位 空保處 承辦人 柏雪翠 執行單位 國立臺北科技大學

成果下載

類型 檔名 檔案大小 說明
期末報告 大氣懸浮微粒特性對能見度影響之研究(期末報告).pdf 18MB

Effect of Atmosphere Particle Properties to Visbility

英文摘要 Visibility is defined as the greatest distance in a given direction at which it is just possible to see and identify a prominent dark object against the skyline with the unaided eye in daytime, visibility degradation is a major problem in atmospheric pollution in many mega cities around the world. The object of this study was to investigate the correlation of visibility with physical and chemical composition of PM2.5 . The field experiments were conducted in four seasons from November 2017 to July 2018 in Qianjin and Qiaotou. Integrating Nephelometer and AE33 was used to measure the aerosol optical properties and compared with the calculated values based upon the measurements of aerosol concentration, size distribution and chemical composition (NH4NO3, (NH4)2SO4, EC and OC). The result indicated the relative humidity was above 80%, the particles usually grew into larger size range in fall and summer, but particle concentration and extinction coefficient in fall was higher than that in summer. The extinction coefficient was the sum of scattering coefficient and absorption coefficient. The ratio of scattering coefficient and absorption coefficient were 90% - 95% and 5% - 10% respectively. The results showed that surface area and volume concentration had a great relationship with extinction coefficient. The RSQr of surface area and volume concentration were more than 0.87. (NH4)2SO4 and NH4NO3 measured in size range of 0.46 µm - 0.7 µm (Qianjin) and 0.3 µm - 0.45 µm (Qiaotou) respectively. The concentration of (NH4)2SO4 and NH4NO3 in Qianjin was higher than in Qiaotou, and the size range were in the visible region between 0.4 µm and 0.7 µm, thus the visibility in Qianjin was lower than in Qiaotou.
英文關鍵字 Extinction coefficient, Particle concentration, Particle size distribution, Water-soluble ionic species