環境資源報告成果查詢系統

107年度戴奧辛及細懸浮微粒排放源輔導管理 (含有害空氣污染物)暨支援環保案件調查計畫

中文摘要 本計畫完成之工作:(1)21家次戴奧辛排放源工廠運作法規符合度現場查核及建檔;(2)116件次戴奧辛排放源申報資料、檢測報告審查與建檔及15家次工廠稽查、定期、改善、操作許可申請等檢測現場監督;(3)8根次排放管道戴奧辛稽查檢測;(4)4根次重點行業管道重金屬排放特性檢測;(5)3根次重點行業管道PM2.5排放特性檢測;(6)2季戴奧辛污染源密集地區及3季環保署測站桃園農工共3處環境空氣戴奧辛濃度監測;(7)蘆竹區海湖坑口工業區異味污染源查證;(8)觀音工業區揮發性有機物污染地圖建置;(9)3廠次含銅污泥處理廠實廠製程及排放管道戴奧辛;(10)協助分析宏宇金屬、六和機械與春源鋼鐵公司污染源使用之溶劑原物料分析揮發性有機物含量、林口火力發電廠PM2.5擴散模擬工作、至敬鵬三廠公司與慶毅公司火災後之環境空氣污染物濃度監測等工作共26件樣品;(11)空污事件現場應變標準作業程序建置。 本計畫審查116件次桃園市境內列管之戴奧辛排放源所申報之檢測報告書、檢測計畫書及其他相關資料,執行15家次列管戴奧辛排放源之檢測現場監督工作,僅有日環公司因檢測公司設備損壞,無法符合採樣規範被要求設備維修重新採樣。 現場查核共計清查21家次戴奧辛排放源,清查工作針對列管廠家之戴奧辛排放源的進料量、焚化設備操作、污染防制設備運轉狀況、採樣設施條件等現場各項操作參數以科學儀器進行查驗,以有效管控各廠防制設備操作狀況,針對不符合法規之6家廠家,提供必要之協助並追蹤其改善的完整性。 執行8根次列管戴奧辛排放源稽查檢測工作,確認立盈環保與水美工程於污染源及防制設備經改善後,戴奧辛有明顯減量效益;清楚力鵬楊梅廠發現燃燒污泥過程是會有較高濃度戴奧辛排放;岦陞公司若全量運轉排放濃度恐會倍數成長。 107年度各戴奧辛排放源之年度總進料量推算之大型焚化爐年度排放量為0.044 g-TEQ/year,中型焚化爐為0.008 g-TEQ/year,小型焚化爐為0.254 g-TEQ/year,電弧爐為2.498 g-TEQ/year,輔助燃料-廢液為0.005 g-TEQ/year,輔助燃料-污泥為0.040 g-TEQ/year,輔助燃料-木屑為0.101 g-TEQ/year,輔助燃料-水煤漿為0.061 g-TEQ/year,鍋爐發電或汽電共生燃煤鍋爐為0.425 g-TEQ/year,火化場為0.00006 g-TEQ/year,銅二級冶煉為0.169 g-TEQ/year,鋁及其他金屬二級冶煉為0.005 g-TEQ/year,其他製程行業別為0.004 g-TEQ/year,107年總排放量為3.614 g-TEQ/year,約占環保署推估之105年度全國戴奧辛年排放量(52.1 g-TEQ/year)之1/14。 完成3處採樣點(大潭電廠辦公大樓、觀音區樹林國小、桃園農工監測站)環境空氣戴奧辛檢測調查,107年6月僅在桃園農工進行監測,其濃度為0.014 pg-TEQ/Nm3;107年8月3處採樣點之平均濃度0.039 pg TEQ/Nm3,範圍介於0.024 ~ 0.052 pg TEQ/Nm3;107年11月3處採樣點之平均濃度0.019 pg TEQ/Nm3,範圍介於0.013 ~ 0.023 pg TEQ/Nm3,其中以大潭電廠辦公大樓監測濃度值最高;觀音工業區之監測值仍較市區為高,與北部地區歷年環境空氣戴奧辛監測數值進行比較與其他都市測站監測濃度相近,3處採樣點之監測值均低於日本周界空氣戴奧辛環境品質基準年平均值0.6 pg-TEQ/Nm3。 本計畫至今已針對燃氣鍋爐、焚化爐、燃油鍋爐、燃煤鍋爐等四種類型燃燒污染源進行PM2.5排放特性調查,其中焚化爐針對不同爐型進行調查,燃油鍋爐則細分針對油品種類、有無防制設備進行調查,燃煤鍋爐則是針對設有不同類型之防制設備進行調查,以FPM2.5與CPM2.5排放結果來看,燃氣鍋爐之排放濃度較低且較穩定,大部分樣品之排放濃度是以FPM為主;焚化爐為則是爐型越大,起停爐次數越少,燃燒狀況越穩定,其排放濃度就較低;燃油鍋爐PM2.5排放調查工作,目前FPM之濃度為未有防制設備之重油鍋爐=有洗滌塔之重油鍋爐>有旋風分離器之重油鍋爐>柴油鍋爐;CPM之濃度為未有防制設備之重油鍋爐>有旋風分離器之重油鍋爐>有洗滌塔之重油鍋爐>柴油鍋爐,因洗滌塔僅可將5酸1鹼去除約60%~70%左右,仍會有大量造成FPM與CPM的前驅氣體逸出,旋風分離器對PM2.5去除效果有限,但可知裝有防制設備之燃油鍋爐仍對於PM2.5仍有一定之去除能力。 於印染整理業之定型機PM2.5排放係數資料可知1 kg的定型助劑會排放3.66 g的PM2.5,以麒勝實業為例,該廠一年運作300天,每天運作24小時,每小時定型助劑使用量為11.25 kg,一年之PM2.5排放量為296 kg,桃園市印染整理業高約180家,定型機PM2.5年排放量可達50公噸。 調查戴奧辛污染潛勢高之行業-含銅處理廠的製程與空污運作現況,發現佶鼎驟冷塔出口通過長逾100公尺煙道進入袋式集塵器後,PCDD/Fs質量濃度不減反增,推測過長管路若其中有殘留前驅物將促進PCDD/Fs再合成,該廠洗滌塔對於煙道氣中PCDD/Fs的去除效率約31.3%;銅鼎防制設備對於PCDD/Fs質量濃度去除效率達99.9%,旋窯及煉銅爐旋風集塵器PCDD/Fs質量濃度結果指出,煉銅爐端較利於生成PCDD/Fs,且其粒狀物濃度高,煙道溫度為240 ℃,接近PCDD/Fs生成之溫度窗(250-450 ℃)。 本計畫執行期間協助分析宏宇金屬、六和機械與春源鋼鐵公司污染源使用之溶劑原物料分析揮發性有機物含量,協助確認空污費申報查驗與污染來源追蹤。林口火力發電廠PM2.5擴散模擬工作、至敬鵬公司三廠與慶毅公司火災後之環境空氣污染物濃度監測、協助確認冠格公司廢氣焚化爐之處理效率等工作。 協助空污事件現場應變標準作業程序建置有利於災害事件發生後的空污應變啟動之判斷機制,並整合所有關於空氣污染事件應變之流程,建立標準作業程序,以利於事件除蒐證並完整紀錄外,確認空氣品質監控及救護疏散作業,俾使意外事件能有效應變處理。
中文關鍵字 環境監測、戴奧辛、細懸浮微粒、揮發性有機物、排放係數

基本資訊

專案計畫編號 經費年度 107 計畫經費 9605 千元
專案開始日期 2018/04/26 專案結束日期 2018/12/31 專案主持人 杜敬民
主辦單位 桃園市政府環境保護局 承辦人 汪正倫 執行單位 財團法人工業技術研究院

成果下載

類型 檔名 檔案大小 說明
期末報告 計畫成果摘要.pdf 0MB

This project is management and assistance of dioxin and fine particle matter emission and supported the investigation of environmental pollution cases(2018)

英文摘要 The job content in the planning includes (1) On-site check and filing of operation regulation compliance for 21 Dioxin emission source plants; (2) check and filing of declared data and test report for 116 Dioxin emission source, and supervision on inspection, regular intervals, improvement and application for operation license of 15 plants; (3) Dioxin inspection of 8 drain pipes; (4) Inspection on heavy metal emission characteristics of 4 key industries; (5) Inspection on pipe PM2.5 emission of 3 key industries; (6) Dioxin concentration monitoring of intensive 2-quarter pollution source area and 3-quarter EPA test station Taoyuan peasants and workers; (7) Odor source verification in Haihu Kengkou Industrial Zone in Luzhu District; (8) VOC pollution map establishment in Guanyin Industrial Zone; (9) Manufacture procedures of three copper sludge treatment plants and pipe Dioxin; (10) Assisted in analyzing solvent raw materials of Hongyu Enterprise CO., LTD, Lioho Machine works, Ltd. and Chun Yuan Steel Industry Co., Ltd Taiwan, analyzing VOC contents, PM2.5 diffusion and simulation work of Linkou Power Plant, and ambient air pollutant concentrations of 26 samples after fire if Chin Poon No.3 plant and Qingyi Company; (11) establishment of air pollution site strain standard job program. This planning audits 116 test reports, test plans and other relevant data of Dioxin emission sources for pipes in Taoyuan City, executes on-site supervision of 15 Dioxin emission sources. Only Rihuan Company is required for equipment maintenance and resampling due to failure to meet sampling specifications because of equipment damage of the test company. Check 21 Dioxin emission sources. Inventory work includes inspection on feed quantity of Dioxin emission sources for the tube manufacturers, operation of incineration equipment, operating condition of pollution control equipment, and sampling facility conditions with scientific instrument, thus effectively controlling operation conditions of control equipment in various plants. For 6 noncompliance plants, provide necessary assistance and follow improved integrity. Conduct inspection on Dioxin emission sources for 8 tubes, and confirm that Dioxin has obvious decrement benefits after pollution source and control equipment improvement of Lying Environmental Technology protection and Super Max Engineering; know well that whether there is high concentration of Dioxin during sludge combustion of Lipeng Yangmei Plant; If Lisheng Company is full operation, emission concentration will be multiplied Based on calculation of total annual feeds for Dioxin emission sources in 2018, annual emission of large incinerators was 0.044g-TEQ/year, annual emission of medium incinerator was 0.008 g-TEQ/year, annual emission of small incinerator was 0.254g-TEQ/year, annual emission of electric-arc furnace was 2.498g-TEQ/year, annual emission of auxiliary fuels - waste liquor was 0.005 g-TEQ/year, annual emission of auxiliary fuels – sludge was 0.040g-TEQ/year, annual emission of auxiliary fuels –bits of wood was 0.101g-TEQ/year, annual emission of auxiliary fuels –water-coal-slurry was 0.061g-TEQ/year, annual emission of boiler power generating or steam and electric coal-fired boilers was 0.425g-TEQ/year, annual emission of crematorium was 0.00006 g-TEQ/year, annual emission of secondary copper smelting was 0.169g-TEQ/year, annual emission of secondary smelting of aluminum and other metals was 0.005 g-TEQ/year, and annual emission of processing industry was 0.004g-TEQ/year. Total emission at 2018 was 3.614g-TEQ/year, which accounted for 1/14 of annual Dioxin emission in 2016 evaluated by EPA (52.1g-TEQ/year). Completed Dioxin detection survey of ambient air in three sampling sites (Datan power plant office building, Guanyin District Shulin primary School, and Taoyuan agricultural and industrial monitoring station). At June 2018, conducted monitoring in Taoyuan agricultural and industrial monitoring station with concentration of 0.014pg-TEQ/Nm3; on August 3, 2018, average concentration of sampling sites is 0.039pg TEQ/Nm3, and range is 0.024 ~ 0.052 pg TEQ/Nm3; on November 3, 2018, average concentration of sampling sites is 0.019pg TEQ/Nm3, and range is 0.013~0.023pg TEQ/Nm3, and monitored concentration values of Datan power plant office building was maximum; monitoring value of Guanyin industrial park was higher than other cities; monitored concentration is close to Dioxin monitoring values of ambient air over years in northern areas; monitored value of 3 sampling sites is lower than 0.6pg-TEQ/Nm3- average value for base year of Dioxin environmental quality of ambient air. So far, the planning has investigated emission performance of combustion source PM2.5 for gas boiler, incinerator, oil burning boiler and coal-fired boiler; for incinerators, conduct investigation on different types of boilers, and conduct investigation on oil types and control equipment based on subdivision of oil burning boilers; for coal-fired boilers, conduct investigation on control equipment of different types; based on emission results of FPM2.5 and CPM2.5, emission concentration of gas boilers is low and stable, and emission concentration of most samples is mainly FPM; for the incinerator, the boiler is larger, starting and ending boilers is fewer, combustion condition is more stable, and emission concentration is lower; based on emission investigation of oil burning boiler PM2.5, current FPM concentration is as follows: heavy oil boiler without control equipment = heavy oil boiler of washing tower > heavy oil boiler with the cyclone separator > diesel boiler for; CPM concentration is as follows: heavy the control equipment without oil boiler>boiler with the cyclone separator>heavy oil boiler of washing tower >diesel boiler. The washing tower can only remove 5 acid and alkaline of about 60%~70%, and there is still a large number of precursor gas which causes FPM and CPM. The cyclone separator’s removal efficiency of PM2.5 is limited, but the oil burning boiler installed the control equipment still has a certain ability to remove PM2.5. Based on PM2.5 emission coefficient data for setting machine of printing and dyeing industry, PM2.5emission for1kg-setting is 3.66g. For Qisheng industrial, if annual operation of 300 days with 24 hours a day, usage amount of setting every hour is 11.25 kg, and annual emission of PM2.5is 296 kg. There are about 180 printing and dyeing enterprises in Taoyuan City, and annual emission of PM2.5 for the setting machine is 50 tons. According to investigation on the industry with high Dioxin pollution potential – processing and air pollution operation conditions of copper processing plant, after Jiding quench tower outlet entering bag collector by gas duct with length of 100 meters, quality concentration of PCDD/Fs is increased; if long tube has left precursors, PCDD/Fs will be promoted to be re-composed, and removal efficiency of bronze tripod control equipment will be about 31.3%; removal efficiency of the bronze tripod control equipment for PCDD/Fs quality concentration is 99.9%; quality concentration results of rotary kiln and copper smelting furnace cyclone dust collector PCDD/Fs point out that the copper smelting furnace is beneficial to generating PCDD/Fs, particle concentration is high, and flue gas temperature is 240℃, close to temperature window (250-450℃) generated by PCDD/Fs. During implementation of program, assisted in analyzing solvents raw materials of source of pollution for Hongyu Enterprise CO., LTD, Lioho Machine works, Ltd. and Chun Yuan Steel Industry Co., Ltd Taiwan to analyze VOC contents, and assisted in confirming declaration and inspection of air pollution charges and pollution source tracking. After Linkou Power Plant PM2.5 diffusion simulation work, fire of No.3 plant of Chin Poon Company and Qingyi Company, conduct monitoringon ambient air pollutant concentration, and assisted in confirming treatment efficiency of waste gas incinerator for Ag Film Technology Co., Ltd.. Assist in standard operating procedures establishment on the air pollution site, which benefits judgment mechanism of air pollution starting after disasters, integrates all processes related to air pollution events, and establishes standard operation procedure, thus collecting evidence of events and achieving complete records, confirming air quality monitoring and rescue operation, and effectively treating accidents.
英文關鍵字 environmental monitoring, dioxin, PM2.5, VOCs, emission factor