環境資源報告成果查詢系統

排放管道及周界中甲基第三丁基醚等4種化合物調查技術開發

中文摘要 本計畫目標為開發排放管道及周界中甲基第三丁基醚、環氧乙烷、1,2-環氧丙烷及2-甲基丙烯酸甲酯等揮發性有機物之調查技術評估，提供行政院環保署環境檢驗所作為建立標準方法之參考。針對排放管道，甲基第三丁基醚、環氧乙烷、1,2-環氧丙烷及2-甲基丙烯酸甲酯，以採樣袋採樣，GC/FID進行分析；針對周界，甲基第三丁基醚、1,2-環氧丙烷及2-甲基丙烯酸甲酯以不銹鋼筒採樣，GC/MS進行分析；針對周界，環氧乙烷以採樣管 (覆蓋溴化氫活性碳)採樣，GC/ECD進行分析。 根據實驗結果，排放管道方面，甲基第三丁基醚、環氧乙烷、1,2-環氧丙烷及2-甲基丙烯酸甲酯之方法偵測極限，分別為0.092 ppmv、0.256 ppmv、0.155 ppmv及0.207 ppmv；準確度分別為105.13%、95.58%、104.31%及98.23%；精密度分別為3.23%、3.07%、2.94%及4.70%。 周界方面，甲基第三丁基醚、環氧乙烷、1,2-環氧丙烷及2-甲基丙烯酸甲酯之方法偵測極限，分別為0.419 ppbv、0.856 ppbv (採樣量以12 Liter計算)、1.934 ppbv及1.116 ppbv；準確度分別為100.27%、97.99% (採樣量以12 Liter計算)、102.74%及100.66%；精密度分別為3.73%、4.74% (採樣量以12 Liter計算)、3.78%及3.60%。 本計畫亦運用上述調查技術開發之採樣及分析條件，完成國內排放管道或周界至少2場次現場調查。此外，本計畫在10月及11月舉行2場次技術擴散課程，並提出調查技術草案，提供環保署作為檢測技術援引之參考。
中文關鍵字 排放管道、周界、揮發性有機物

基本資訊

專案計畫編號 EPA-107-1602-02-02 經費年度 107 計畫經費 2780 千元
專案開始日期 2018/04/11 專案結束日期 2018/12/31 專案主持人 王永立
主辦單位 環檢所 承辦人 陳重方 執行單位 工業技術研究院

成果下載

類型 檔名 檔案大小 說明
期末報告 期末報告v1.4(定稿本).pdf 7MB

Development of Sampling and Analytical Methods for Methyl tert-Butyl Ether and other 3 Compounds in Stack and Ambient Air

英文摘要 The objective of this project was to develop sampling and analytical methods for volatile organic compounds, including methyl tert-butyl ether (MTBE), ethylene oxide (EO), propylene oxide (PO), and methyl methacrylate (MMA) in stacks and ambient air for Environmental Analysis Laboratory, EPA to establish standard operation methods. As stacks, MTBE, EO, PO, and MMA were sampled using gas sampling bags and then analyzed by GC/FID. As for ambient air, MTBE, PO, and MMA were sampled using canisters and then analyzed by GC/MS, and EO was sampled using sampling tubes packed with activated carbon coating hydrogen bromide and then analyzed by GC/ECD. Based on experimental results, as for stacks, the detection limits of MTBE, EO, PO, and MMA were 0.092 ppmv, 0.256 ppmv, 0.155 ppmv and 0.207 ppmv, respectively. Accuracy were 105.13%, 95.58%, 104.31% and 98.23%, respectively. Precision were 3.23%, 3.07%, 2.94% and 4.70%. As for ambient air, the detection limits of MTBE, EO, PO, and MMA were 0.419 ppbv, 0.856 ppbv (sampling volume was 12 liter), 1.934 ppbv and 1.116 ppbv, respectively. Accuracy were 100.27%, 97.99% (sampling volume was 12 liter), 102.74% and 100.66%, respectively. Precision were 3.73%, 4.74% (sampling volume was 12 liter), 3.78% and 3.60%. The sampling and analytical methods developed in this project were proven to be practical by surveying at least 2 field samplings (air emission stacks or ambient air). Besides, two technical communication seminars were taken place in October and November. All the study results were reported in the technical drafts for EPA’s reference.
英文關鍵字 stack, ambient air, volatile organic compounds