環境資源報告成果查詢系統

土壤及地下水油品污染溯源發展計畫

中文摘要 本計畫主要分為三部份。第一部份是建立新鮮汽油的鑑識技術。於計劃期間取得3座煉油廠共27個成品汽油與40個摻配原料油,以及60座加油站共180個新鮮汽油。本計畫採用詳細碳氫化合物分析儀和氣相層析質譜儀來獲得汽油之化學指紋圖譜。經篩選適當的化合物並計算診斷比值後,以主成份分析法建立供應源鑑識技術,成功鑑別中油與台塑之新鮮汽油。 第二部份是以不動桿菌(Acinetobacter venetianus)和煉油廠之活性污泥進行含硫柴油的菌蝕試驗,並以硫含量指標化合物診斷比值與硫含量所建立之回歸關係式回推柴油硫含量,搭配各時期的硫含量管制標準,建立柴油洩漏時間推估技術。 第三部份是提出油品鑑識技術推廣與應用策略之構想,期望能實際運用油品鑑識技術,釐清污染行為人之責任歸屬。
中文關鍵字 環境法醫、新鮮汽油、詳細碳氫化合物分析、氣相層析質譜儀、指紋圖譜、診斷比值、主成份分析、定年、柴油、發明專利

基本資訊

專案計畫編號 EPA-107-GA03-03-A179 經費年度 107 計畫經費 13300 千元
專案開始日期 2018/06/01 專案結束日期 2019/11/30 專案主持人 黃德坤
主辦單位 土污基管會 承辦人 李嘉哲 執行單位 台灣中油股份有限公司

成果下載

類型 檔名 檔案大小 說明
期末報告 期末報告_公開版.pdf 15MB 期末報告公開版

Source Identification Development Plan for Soil and Groundwater Oil Contamination

英文摘要 There are three parts in this project. Firstly, we collected 27 fresh gasoline and 40 blending stocks from 3 petroleum refineries and 180 fresh gasoline from 60 gas stations during the project period. The detailed hydrocarbon analysis (DHA) and GC/MS were employed to acquire chemical fingerprints of gasoline. After suitable compounds were selected for diagnostic ratio calculation, we successfully identified fresh gasoline from CPC and FPCC using principal components analysis (PCA). Secondly, we used Acinetobactor venetianus and petroleum refinery activated sludge to simulate the diesel biodegradation in environment and then established the correlation between diagnostic ratios of specific sulfur containing compounds and sulfur content. By applying such correlation to the regulatory timetable of diesel sulfur limit, we develop an approach for the age-dating of the diesel spills. Thirdly, we proposed the idea of promoting and implementing this petroleum identification method into real world application, with the hope of clarifying the responsibilities between two parties in the incidence.
英文關鍵字 Environmental forensics, Fresh gasoline, Detailed hydrocarbon analysis, GC/MS, Chemical fingerprint chromatogram, Diagnostic ratio, Principal component analysis, Age dating, Diesel, Invention patent