環境資源報告成果查詢系統

排放管道及周界中氯丁二烯等有機空氣污染物調查技術開發

中文摘要 計畫目標為開發氯丁二烯、三氯甲苯、1,2-二氯丙烷、乙酸乙烯酯、溴甲烷、氯甲烷、氯丙烯、1,1-二氯乙烯及甲基丙烯酸甲酯等有機空氣污染物之調查技術。針對排放管道，氯丁二烯、1,2-二氯丙烷、溴甲烷、氯甲烷、氯丙烯及1,1-二氯乙烯，以採樣袋採樣，GC/ECD進行分析；乙酸乙烯酯及甲基丙烯酸甲酯，以採樣袋採樣，GC/FID進行分析；三氯甲苯以吸收液採樣，GC/MS進行分析。針對周界，目標物種皆以不銹鋼筒採樣，GC/MS進行分析。 根據實驗結果，排放管道方面，氯丁二烯、三氯甲苯、1,2-二氯丙烷、乙酸乙烯酯、溴甲烷、氯甲烷、氯丙烯、1,1-二氯乙烯及甲基丙烯酸甲酯之方法偵測極限，分別為0.037 ppmv、4.798×10-3 ppmv、0.036 ppmv、0.210 ppmv、0.031 ppmv、0.034 ppmv、0.038 ppmv、0.035 ppmv及0.189 ppmv；準確度分別為103.14%、97.71%、107.21%、98.46%、105.98%、103.59%、101.73%、106.16%及98.23%；精密度分別為5.37%、6.73%、6.95%、2.03%、4.65%、6.81%、5.10%、5.50%及2.27%。 周界方面，氯丁二烯、三氯甲苯、1,2-二氯丙烷、乙酸乙烯酯、溴甲烷、氯甲烷、氯丙烯、1,1-二氯乙烯及甲基丙烯酸甲酯之方法偵測極限，分別為0.388 ppbv (full scan) 及0.143 ppbv (SIM mode)、0.467 ppbv (full scan) 及0.188 ppbv (SIM mode)、0.183 ppbv (SIM mode)、0.716 ppbv (SIM mode)、0.173 ppbv (SIM mode)、0.179 ppbv (SIM mode)、0.164 ppbv (SIM mode)、0.139 ppbv (SIM mode) 及0.185 ppbv (SIM mode)。氯丁二烯之準確度為91.13% (full scan) 及101.98% (SIM mode)，精密度為6.61% (full scan) 及7.92% (SIM mode)；三氯甲苯之準確度為106.78% (full scan) 及105.31% (SIM mode)，精密度為6.85% (full scan) 及7.47% (SIM mode)。 本計畫亦運用上述調查技術開發之採樣及分析條件，完成國內排放管道或周界至少4場次現場調查。此外，本計畫在7月及10月舉行2場次技術擴散課程，並提出調查技術草案。
中文關鍵字 排放管道、周界、揮發性有機物

基本資訊

專案計畫編號 經費年度 108 計畫經費 3100 千元
專案開始日期 2019/04/03 專案結束日期 2019/12/31 專案主持人 王永立
主辦單位 環檢所 承辦人 潘銓泰 執行單位 工業技術研究院

成果下載

類型 檔名 檔案大小 說明
期末報告 108環檢所氯丁二烯期末報告(定稿本).pdf 9MB

Development of Sampling and Analytical Methods for Chloroprene and other 8 Compounds in Stacks and Ambient Air

英文摘要 The objective of this project was to develop sampling and analytical methods for volatile organic compounds, including chloroprene, benzotrichloride, 1,2-dichloropropane, vinyl acetate, bromomethane, chloromethane, allyl chloride, 1,1-dichloroethene, and methyl methacrylate in stacks and ambient air. As for stacks, chloroprene, 1,2-dichloropropane, bromomethane, chloromethane, allyl chloride, and 1,1-dichloroethene were sampled using gas sampling bags and then analyzed by GC/ECD; vinyl acetate, and methyl methacrylate were sampled using gas sampling bags and then analyzed by GC/FID; benzotrichloride were sampled using absorption solvent and then analyzed by GC/MS. As for ambient air, all the target compounds were sampled using canisters and then analyzed by GC/MS. Based on experimental results, as for stacks, the detection limits of chloroprene, benzotrichloride, 1,2-dichloropropane, vinyl acetate, bromomethane, chloromethane, allyl chloride, 1,1-dichloroethene, and methyl methacrylate were 0.037 ppmv,4.798×10-3 ppmv, 0.036 ppmv, 0.210 ppmv, 0.031 ppmv, 0.034 ppmv, 0.038 ppmv, 0.035 ppmv, and 0.189 ppmv, respectively. Accuracy were 103.14%, 97.71%, 107.21%, 98.46%, 105.98%, 103.59%, 101.73%, 106.16%, and 98.23%, respectively. Precision were 5.37%, 6.73%, 6.95%, 2.03%, 4.65%, 6.81%, 5.10%, 5.50%, and 2.27%, respectively. As for ambient air, the detection limits of chloroprene, benzotrichloride, 1,2-dichloropropane, vinyl acetate, bromomethane, chloromethane, allyl chloride, 1,1-dichloroethene, and methyl methacrylate were 0.388 ppbv (full scan) and 0.143 ppbv (SIM mode), 0.467 ppbv (full scan) and 0.188 ppbv (SIM mode), 0.183 ppbv (SIM mode), 0.716 ppbv (SIM mode), 0.173 ppbv (SIM mode), 0.179 ppbv (SIM mode), 0.164 ppbv (SIM mode), 0.139 ppbv (SIM mode), and 0.185 ppbv (SIM mode), respectively. Accuracy of chloroprene were 91.13% (full scan) and 101.98% (SIM mode); and precision were 6.61% (full scan) and 7.92% (SIM mode). Accuracy of benzotrichloride were 106.78% (full scan) and 105.31% (SIM mode); and precision were 6.85% (full scan) and 7.47% (SIM mode). The sampling and analytical methods developed in this project were proven to be practical by surveying at least 4 field samplings (stacks or ambient air). Besides, two technical communication seminars were taken place in July and October. All the study results were reported in the technical drafts for EPA’s reference.
英文關鍵字 stack, ambient air, volatile organic compounds