環境資源報告成果查詢系統

製程硫酸與鈣系副產物資源化之研究計畫

中文摘要 本研究以鋼鐵業轉爐石副產物與半導體業製程廢硫酸為原料進行生成反應,開發轉爐石與製程廢硫酸回收再利用程序,實驗結果顯示可將轉爐石之鈣與鐵成分,分別有效轉化成硫酸鈣粉體/晶鬚與硫酸鐵絮凝劑。本研究製備生成之無水硫酸鈣純度為80%、亨特白度為88度(%),以水熱法再處理可生成長度約為160 μm、長徑比約為30之硫酸鈣晶鬚,硫酸鈣晶鬚為具有高成本效益的綠色材料,可以廣泛充填於塗料、聚合物、橡膠、造紙、陶瓷等材料,改善其物理,化學和機械性能。本研究製備生成之硫酸鐵溶液,可應用於廢水處理作為絮凝劑,於廢水酸鹼度(PH值)2~12間均可達到約90%之磷酸鹽去除率,可有效降低水溶液中磷酸鹽濃度;生成之硫酸鐵絮凝劑對於含IPA有機廢水,實驗結果顯示亦可有效降低COD去除率達到80%,與市場商品效能相近。
中文關鍵字 轉爐石、晶鬚、硫酸

基本資訊

專案計畫編號 EPA-110-XB01 經費年度 110 計畫經費 2000 千元
專案開始日期 2021/01/01 專案結束日期 2021/11/30 專案主持人 顧洋
主辦單位 回收基管會 承辦人 廖淑秋 執行單位 國立臺灣科技大學 化學工程系

成果下載

類型 檔名 檔案大小 說明
期末報告 (F結案定稿)製程硫酸與鈣系副產物資源化之研究計畫_期末報告.pdf 5MB

Research plan of industrial by-products of sulfuric acid and calcium recycling

英文摘要 In this study, an effective process was proposed to recover BOFS (Basic oxygen furnace slag) and spent sulfuric acid. The calcium and iron contained in BOFS were converted to calcium sulfate powder/whisker and ferric sulfate flocculant, respectively. The anhydrous calcium sulfate fabricated in this study was with purity of 80% and Hunter brightness of 88%. Calcium sulfate whisker fabricated in this study was with length of 160 μm and aspect ratio of 30 by hydrothermal method. Ferric sulfate, another product fabricated in this study, was demonstrated to be an effective flocculant for phosphorus removal from aquatic solution, about 90% of phosphorus was removed for aquatic solutions between pH 2-12. The COD removal reached 80% for wastewater containing IPA, which exhibited similar removal efficiency comparing to a commercial flocculant.
英文關鍵字 basic oxygen furnace slag, whisker, spent sulfuric acid