環境資源報告成果查詢系統

110年度雲林縣離島工業區揮發性有機物查核及有害空氣污染物調查計畫

中文摘要 本計畫主要的工作項目為專案列管離島工業區揮發性有機物污染源管制及有害空氣污染物調查之業務。管制目的為監督離島工業區揮發性有機物污染源之污染排放,並進行揮發性有機物污染源查核、檢測作業與後續追蹤管制作業,以提昇離島工業區揮發性有機物及有害污染物管制及排放減量成效,以維護本縣空氣品質並減少對於民眾健康的衝擊。自決標日(110年02月24日)開始執行迄今,均依合約規定、原規劃之工作項目及執行方法,並於執行截止日前(110年12月31日)完成期中報告工作量,其主要成果摘要如下: (一) 列管石化製程排放管道及防制設備法規符合度查核共完成30製程,查核結果均符合規定,分析結果均符合操作許可證排放標準。 (二) 查核台塑麥寮廠甲基丙烯酸甲酯廠109年第1季申報空污排放量排放係數填寫錯誤,導致申報錯誤,實際109空污費申報量應修正為0.138T/Y,該廠於第1季原申報0.164T,實際應為0.036T,已要求業者進行修改。 (三) 南亞海豐總廠馬來酐廠之PF03管道進行現場查核時,因該管道僅供開車時使用,其VOCS申報排放量應使用係數推估,而非使用產品推估,其VOCS排放量應修正為0.00167T/Y,已要求業者進行修改。 (四) 離島工業區廢氣燃燒塔已完成43座法規符合度查核,皆依廢氣燃燒塔使用計畫書所核定內容進行操作;另廢氣燃燒塔使用事件日統計至110年12月31日為86日。 (五) 協助進行離島工業區重大工安事件或燃燒塔因製程無預警跳車緊急排放進行上、下風採樣共執行2件次,分別為110年3月24日南亞異壬醇廠火災事件及110年4月9日塑化輕油裂解一廠製程異常緊急排放,並委由上準環境檢測公司以NIEA A715.15B分析苯及甲苯等共87種物質,皆未超過周界標準。 (六) 針對密閉及氣且經防制設備處理之固定頂及內浮頂儲槽法規符合度查核共261座查核結果業者均依規定進行操作;另儲槽設備元件稽查檢測作業完成11座儲槽共250個,均未發現洩漏。 (七) 外浮頂儲槽以GasFind IR及FID進行其封氣設備縫隙洩漏偵測及儲槽縫隙寬度查核,共完成10座查核,皆符合法規符合度。 (八) 列管儲槽開槽清洗作業前之油氣處理,進行其油氣收集方法及排氣處理技術現場查核共完成10座,皆符合法規符合度。 (九) 列管裝載場法規符合度查核共30座,查核的重點包括其裝載之物料實際蒸氣壓及年裝載量、防制設備效率、裝載操作紀錄操作時間、裝載量及裝載之物料等各項紀錄皆符合相關規定。 (十) 製程設備元件洩漏檢測共完成30廠次12,038個設備元件,搭配紅外線洩漏篩檢(GasFindIR)共62小時02分,其中大於洩漏定義值(1,000ppm)共32個,業者均依規定於24小時內完成修護並經承辦人員確認無誤,大於洩漏管制值者共有12個,目前共10顆已完成告發,塑化麥寮三廠輕油裂解二廠2個尚未告發,另要求業者提送元件修護報告書。此外,發現台塑麥寮廠線性低密度聚乙烯廠2點檢測超過10,000 ppm,經確認為2處管線破損,已完成告發。 (十一) 掛牌複測元件修護時間查核共完成502個,發現台塑聚乙烯醋酸乙烯酸酯廠、塑化輕油廠、台化苯乙烯廠及大連化工麥寮廠共4廠資料誤植,已要求業者提供相關修護資料,並立即修正。 (十二) 已完成19座廢水處理設施及1處廢水收集系統,並發現塑化麥寮三廠(輕油裂解二廠) 現場人孔蓋(屬廢水收集系統),現場測得最高淨檢值73,574 ppm,因現行「揮發性有機物空氣污染管制及排放標準」針對廢水收集系統僅針對廢水液面不得與大氣接觸進行管制,並未訂定洩漏標準,故已要求業者進行改善避免異味逸散。 (十三) 已完成15座測15座冷卻水塔之採樣分析,依據分析報告各廠皆符合法規標準5 mg/L,另外於110年7月29日進行台化海豐廠苯乙烯三廠冷卻水塔EJ71水中揮發性有機物稽查檢測採樣,其檢測結果顯示入水端VOCs濃度0.552mg/L(其中主要為乙苯0.488mg/L、苯乙烯0.0427mg/L) ,其排放濃度確實有偏高之情形,已要求業者加強管理。 (十四) 雲林縣空氣污染防制費中揮發性有機物之13項個別物種排放量,二甲苯排放量最多,甲苯次之,其有害空氣污染物主要分布於六輕工業園區、斗六工業園區及雲林科技產業園區 (十五) 進行縣內特殊性工業區監測站提送之採樣行程進行現場人工監測檢測作業之文件及現場查核共完成10站查核,共計發現有四湖、土庫及崙背3個測站,因校方施工或附近居民要求而有人工監測設施位移之情事,業者變更原設位置並未向主管機關進行通報或說明原因。
中文關鍵字 輕油廠、廢水廠、氣密量測、設備元件、燃燒塔(flare) 、苯(Benzene)、甲苯(Toluene)、二甲苯(Xylene)

基本資訊

專案計畫編號 YLEPB-110-026 經費年度 110 計畫經費 14400 千元
專案開始日期 2021/02/24 專案結束日期 2021/12/31 專案主持人 林清標
主辦單位 雲林縣環境保護局 承辦人 廖俊傑 執行單位 台灣曼寧工程顧問股份有限公司

成果下載

類型 檔名 檔案大小 說明
期末報告 110年度雲林縣離島工業區揮發性有機物查核及有害空氣污染物調查計畫(定稿).pdf 23MB

The 2021 Project of VOC inspection and Hazardous air pollutants investigation plan in offshore industrial zones, Yunlin County

英文摘要 The major item of work in this plan is the project monitoring of volatile organic compounds pollution source control and hazardous air pollutant investigation in the industrial area of outlying islands. The purpose of the control is to supervise the emission of volatile organic compounds in the industrial areas of outlying islands, and to proceed with the check, inspection, and follow-up control of the pollution sources of the volatile organic compounds to improve the effectiveness of the control and emission reduction of volatile organic compounds and harmful pollutants in the industrial areas of outlying islands, as well as maintaining this County’s air quality and reducing the impact on people’s health. It has been carried out since the implementation of the bid date (February 24, 2021) in accordance with the contract provisions, the original planned works and implementation methods, and the interim report was completed before the implementation deadline (December 31, 2021). The summary of the major results is as follows: (1) A total of 30 manufacturing processes in the compliance check on controlled petrochemical manufacturing process and control equipment requirements were completed, and the inspection results complied with the regulations. (2) Checking that the Methyl Methacrylate (MMA) Plant at Formosa Plastics’ Mailiao Plant in the first quarter of 2020 reported incorrectly filling in the discharge coefficient for air pollution emissions, which led to an incorrect reporting. The 2020’s air pollution fee declaration should be revised to 0.138T/Y. The Plant originally declared 0.164T in the first quarter, while the actual value should be 0.036T, and the Plant has been asked to make a correction. (3) When the on-site verification of the PF03 pipeline of the Haifeng Maleic Anhydride Plant of Nan Ya Plastics Corporation, and because the pipeline is only used for driving, the VOCS reported emissions should be estimated by using coefficients instead of products. Its VOCS emissions should be amended to 0.00167T/Y, and the Plant has been asked to make a correction. (4) A total of 43 exhaust gas combustion towers in the industrial area of outlying islands have completed compliance check of laws and regulations, which were operated in accordance with the contents approved in the exhaust gas combustion tower usage plan; in addition, the use of exhaust gas combustion towers was counted as 86 days as of December 31, 2021. (5) For assisting in major industrial safety incidents in the industrial area of outlying islands or emergency emissions of combustion towers because of unwarned jump out of a vehicle during the manufacturing process, a total of 2 pieces/times were carried out on the weather and leeward sampling, which were respectively the fire incident of the Isononyl Alcohol Plant, Nan Ya Plastics Corporation, on March 24, 2021, and an abnormal emergency discharge in the manufacturing process of the No. 1 Light Oil Cracking Plant on April 9, 2021, and a total of 87 substances such as benzene and toluene were analyzed by Eurofins SunDream Environmental Technical Co. Ltd. by using NIEA A715.15B. The sampling and analysis results did not exceed the Perimeter Emission Standards. (6) Aiming at a total of 261 inspection results for compliance check on air-tight standing tank and internal floating roof tank that have been treated by control equipment, the industry showed that its performance operation complied with regulations; in addition, a total of 11 storage tanks with 250 equipment components have been inspected and tested and none of the test results showed any leakage. (7) The external floating roof tank used GasFind IR and FID to conduct leak detection of its sealing equipment gap and checked the gap width of the storage tank. A total of 10 inspections have been completed, all of which complied with laws and regulations. (8) For the gassing of oils before the cleaning operation of the controlled storage tanks, a total of 10 on-site inspections of its oil and gas collection methods and exhaust gas treatment technology have been completed, all of which complied with laws and regulations. (9) There were 30 compliance checks for the controlled loading areas. The focus of the check included the actual vapor pressure and annual loading volume of the materials loaded, the efficiency of control equipment, the operating time of the loading operation record, and the loaded material records complied with relevant regulations. (10) A total of 12,038 manufacturing process equipment component leakage tests were completed in 30 factories, totaling 62 hours and 2 minutes with infrared leak detection (GasFind IR). 32 of them were greater than the defined leak rate (1,000 ppm). The repairs were completed within 24 hours and confirmed by the contractor. A total of 12 were greater than the leakage control value. At present, a total of 10 have been reported, and No. 2 of the Plasticizer Mailiao No. 3 Light Oil Cracking Plant has not been reported. A component repair report was requested to commit. In addition, it was found that the linear low-density polyethylene plant at Formosa Plastics’ Mailiao Plant exceeded 10,000 ppm at two points, and it was confirmed that two pipelines were damaged. They were reported thereto as well. (11) A total of 502 repair time inspections of registered retested components were completed, and it was found that the data of 4 plants in the Formosa Plastics Polyethylene Vinyl Acetate Plant, Light Oil Plant, Formosa Styrene Plant and Dalian Chemical Mailiao Plant submitted incorrect data. The companies have been asked to provide relevant repair information and immediately make a correction. (12) 19 wastewater treatment facilities and 1 wastewater collection system were completed, and it was found that the highest net inspection value measured on site of the manhole cover (wastewater collection system) of the Plasticizer Mailiao No. 3 (No. 2 Light Oil Cracking Plant) was 73,574 ppm. The current “Volatile Organic Compounds Air Pollution Control and Emission Standards” only control the wastewater collection system to prevent the liquid surface of the wastewater from contacting the atmosphere without setting a leakage standard; therefore, the companies have been required to make improvements to avoid the spread of odors. (13) The sampling and analysis of 15 cooling water towers were completed. According to the analysis report, each plant met the regulatory standard of 5 mg/L. In addition, on July 29, 2021, the inspection and sampling of the water volatility of the cooling water tower EJ71 of the No. 3 Styrene Plant of the Formosa Haifeng Plant was carried out. The results showed that the VOCs concentration at the water inlet was 0.552mg/L (mainly, ethylbenzene was 0.488mg/L and styrene was 0.0427mg/L). The discharge concentration was indeed high, and the companies have been requested to strengthen the management. (14) Among the 13 individual species of volatile organic compounds in the air pollution control fee of Yunlin County, xylene was emitted the most, followed by toluene. Its harmful air pollutants were mainly distributed in the Sixth Naphtha Cracker Industrial Park, Douliu Industrial Park and Yunlin Technology Industrial Park. (15) For carrying out the sampling itinerary submitted by the monitoring station in the County’s special industrial park, proceeding with on-site manual monitoring and inspection, a total of 10 inspection stations were completed. Three monitoring stations in Sihu, Tuku and Lunbei were found to have monitoring facility displacement because of the schools’ construction or the requirements of nearby residents. The company did not notify or explain the reason for changing the original location to the competent authority.
英文關鍵字 fixed roof tank、flare、Component