環境資源報告成果查詢系統

奈米溶液型二氧化鈦光觸媒披覆技術開發與應用

中文摘要 近二十年來,紫外線/光觸媒程序受到許多的學者重視,也投入相當多的研究,最初的結果均指出能有效的去除甚至礦化水中多種有機物,處理過的物種包括有一般的有機物(揮發性有機物、酚類、酸類、氯苯類)、染料、農藥等;另外對於水中之有害陰離子,如NO2-、CN-等亦能有效的加以去除;而近來市場對光觸媒材料的需求,更因為光觸媒的抗菌殺菌以及對建築材料具有防污自淨等功能,逐漸被大眾市場所接受,甚至有迫切的需求。然而,光觸媒反應原理在科學上逐漸為學者確知及定量後,雖然已成功地開發出分解不同有機污染物的光觸媒材料,但成功商業化應用的案例並不多見,主要的原因即在於光觸媒材料本質的限制與光觸媒在載體之附著技術無法突破所致。本計畫主要目的在研究光觸媒披覆特性,並嘗試進行光觸媒改質,使得光觸媒可以有效的批覆於各類基材上。而在披覆基材選擇的部分,將以玻璃、磁磚、金屬等作為光觸媒之固定基材。 經由實驗結果顯示,光觸媒批覆除了要先進行光觸媒改質外,必須配合基材前處理及噴槍、噴嘴的控制,才可以將光觸媒披覆於基材上,且披覆膜厚外觀良好。此外,在有機污染物之反應實驗中,顯示可有效分解空氣及液相中之污染物。
中文關鍵字 光催化,批覆,二氧化鈦,,,

基本資訊

專案計畫編號 EPA-084930107--- 經費年度 093 計畫經費 4000 千元
專案開始日期 2004/05/01 專案結束日期 2004/12/31 專案主持人 顧洋
主辦單位 永續發展室(停用) 承辦人 執行單位 國立台灣科技大學

成果下載

類型 檔名 檔案大小 說明
期末報告 0000033713.pdf 107MB [期末報告]公開完整版

Titanium dioxide photocatalysis tcoating echnological development and application

英文摘要 Heterogeneous semiconductor photocatalysis reveals an emerging demand of environmental catalysis with significant potential to detoxify noxious organic pollutants in an effective manner. A variety of semiconductor materials have been investigated for the usage due to the growing interest in the development of inexpensive and efficient methodologies to reduce environmental problems. TiO2 is the most popular semiconductor photocatalyst been investigated because of its stability, nontoxicity, availability, and cost-effectiveness, as well as its ability to degrade a variety of harmful pollutants such as VOCs and organic substance in water. However, the main obstacles for the application of photocatalyst such as coating technology and adhesion problem were not solved yet, especially for its extending practice for general customers. The objective of this research was to develop a simple and innovate processing method for photocatalyst technology and to investigate the reaction behavior of the photooxidation of both gas-phase volatile organic compounds and liquid-phase organic compound in the presence of titanium dioxide. The coverage and surface properties TiO2 layer ocated on different substrates by various coating technologies will be examined. Various substrates such as stainless steel, PMMA sheet, ceramic and glass were used in this experiment and excellent coating appearance for all materials could be achieved via unique modification of titanium dioxide. The research also includes the investigation relating to the effect of photocatalyst and base substrate on UV photocatalysis. Experimental result has been shown to be feasible to decompose gas-phase and liquid-phase organic compounds.
英文關鍵字 photocalysis,coating,titanium dioxide