環保專案成果報告查詢系統

專案計畫編號	EPA-105-GA12-03-A289
經費年度	105
計畫經費	18,800 千元
預算科目	土壤及地下水污染調查、應變及整治之推動
專案開始日期	2016/02/18
專案結束日期	2017/05/18
專案主持人	王聖瑋
主辦單位	土污基管會
承辦人	陳俞穎
執行單位	業興環境科技股份有限公司
專案分類	土壤及地下水
中文關鍵字	新興污染物、地下水水質調查、地下水污染物候選清單
英文關鍵字	Emerging Contaminants, Groundwater quality survey, Groundwater contaminants candidate list
協同主持人	劉志忠
共同主持人
計畫聯絡人	蕭方歌
計畫聯絡電話	02-27691002#104
計畫聯絡信箱	fanco@setl.com.tw

中文摘要	本計畫彙整國內外關注之持久性有機物、環境荷爾蒙等物質，比對國外管制情況檢討地下水管制標準，篩選關切物質辦理地下水關切物質流布與影響調查、地下水關切農藥潛勢與環境流布探討及地下水關切物質優先順序更新等工作。地下水關切物質流布與影響調查，針對五氯苯、5種塑化劑及7種金屬及兩性元素，依據原物料使用及歷年環境監測數據，針對高潛勢區域辦理地下水調查，共50口次地下水既有監測井採樣檢測工作，綜整調查結果以硼(0.025~1.33 mg/L)及DEHA(2×10-5~9.64×10-4 mg/L)調查最為顯著，其中地下水硼濃度超出國外管制限值0.3 mg/L，可能為運作關切物質所導致，建議後續考量於污染潛勢區持續辦理監測及調查之可行性，並視需求評估地下水新增列管之必要性。比對放流水、飲用水等其他標準中列管之農藥項目，以及使用量較大且毒性較高之農藥，篩選26項關切農藥，針對水稻區及蔬菜區辦理環境流布及地下水潛勢調查，共設置10口簡易井，依據作物生長期程分階段採樣檢測，並比對農民用藥紀錄，其中以有機磷類之托福松、福瑞松及除草劑丁基拉草檢出最顯著，檢出濃度均為ppb等級，上述農藥均為國內廣泛使用之農藥，建議後續視需求考量持續監測之必要性，累積地下水基線資料。建立本計畫調查之關切物質基本性質及危害資料，並延續前期計畫成果，更新地下水關切物質清單至163項，排列優先序列，依據排序成果及地下水歷年檢出成果篩選出建議優先關切之物質（包含DEHP及硼），提出後續調查規劃及管制策略建議。
中文關鍵字	新興污染物、地下水水質調查、地下水污染物候選清單

中文摘要

本計畫彙整國內外關注之持久性有機物、環境荷爾蒙等物質，比對國外管制情況檢討地下水管制標準，篩選關切物質辦理地下水關切物質流布與影響調查、地下水關切農藥潛勢與環境流布探討及地下水關切物質優先順序更新等工作。地下水關切物質流布與影響調查，針對五氯苯、5種塑化劑及7種金屬及兩性元素，依據原物料使用及歷年環境監測數據，針對高潛勢區域辦理地下水調查，共50口次地下水既有監測井採樣檢測工作，綜整調查結果以硼(0.025~1.33 mg/L)及DEHA(2×10-5~9.64×10-4 mg/L)調查最為顯著，其中地下水硼濃度超出國外管制限值0.3 mg/L，可能為運作關切物質所導致，建議後續考量於污染潛勢區持續辦理監測及調查之可行性，並視需求評估地下水新增列管之必要性。比對放流水、飲用水等其他標準中列管之農藥項目，以及使用量較大且毒性較高之農藥，篩選26項關切農藥，針對水稻區及蔬菜區辦理環境流布及地下水潛勢調查，共設置10口簡易井，依據作物生長期程分階段採樣檢測，並比對農民用藥紀錄，其中以有機磷類之托福松、福瑞松及除草劑丁基拉草檢出最顯著，檢出濃度均為ppb等級，上述農藥均為國內廣泛使用之農藥，建議後續視需求考量持續監測之必要性，累積地下水基線資料。建立本計畫調查之關切物質基本性質及危害資料，並延續前期計畫成果，更新地下水關切物質清單至163項，排列優先序列，依據排序成果及地下水歷年檢出成果篩選出建議優先關切之物質（包含DEHP及硼），提出後續調查規劃及管制策略建議。

中文關鍵字

新興污染物、地下水水質調查、地下水污染物候選清單

類型	檔名	檔案大小	說明	最新版公開日期
期末報告	EPA-105-GA12-03-A289書面正式報告(本文+附錄).pdf	48MB		2017/10/1 上午 12:00:00

摘要	The purposes of this project is to investigate the groundwater contamination potential of hazardous materials and its distribution. First of all, we collected the emerging contaminants by international concern, including persistent organic pollutants (POPs) and endocrine disrupting chemicals (EDCs). In order to understand the distribution of the contaminants in the environment. We reviewed the current groundwater standards against the collected contaminants, and screened out the contaminants which require further investigation. By knowing the distribution of the contaminants in the environment. We were able to rearrange Groundwater contaminants candidate list. The concerned emerging contaminants include Pentachlorobenzene, Dicyclohexyl Phthalate (DCHP), Diphenyl phthalate (DPHP), Di-n-hexyl phthalate (DNHP), Di-n-propyl phthalate (DPrP), Di (2-ethylhexyl) adipate (DEHA), Boron, lithium and Tungsten etc. Groundwater investigation of 50 groundwater monitoring wells was conducted based on the use of raw materials and historical environmental monitoring data .The results showed that DEHA (0.025~1.33 mg/L) and Boron (2×10-5~9.64×10-4 mg/L) were more significant than other substances. The concentration of Boron exceeded the foreign control limit of 0.3 mg/L, and may be caused by the operation of industrial activities. It is recommended that monitoring and investigation of groundwater be implemented continuously, and review whether the groundwater standards needs to be amended. This project also aims to investigate the possibility of concerned pesticides in the groundwater. Concerned pesticides include Chlordane, Terbufos, Phorate, Paraquat, Butachlor and so on, totally 26 species. The survey area was divided into rice area and vegetable area. A total of 10 simple wells were set up in this project. Phased sampling test was conducted according to the crop growth period, and the results were compared to the farmers pesticide usage record. The result of the investigation showed that Terbufos, Phorate and Butachlor were more significant than others, while the detection of concentrations were ppb level. This project referred to domestic and foreign research reports and databases to establish physical-chemical and toxicology data for the concerned contaminants. At present, data have been gathered for 163 contaminant candidates. Base on the contaminant candidate list and the results of the historical groundwater investigation. Boron and Di(2-ethylhexyl) phthalate(DEHP) were identified to be the priority controlled contaminants and strategies of controlling and survey planning were purposed by this project. This study recommend the government to continuously focus on the environment of the river basins. In addition, the results if this project provided fundamental information for amending the monitoring standard and regulating standards of groundwater in the future. Aforementioned results and suggestions could be submitted to competent authorities as practical implementation references.
英文關鍵字	Emerging Contaminants, Groundwater quality survey, Groundwater contaminants candidate list

摘要

The purposes of this project is to investigate the groundwater contamination potential of hazardous materials and its distribution. First of all, we collected the emerging contaminants by international concern, including persistent organic pollutants (POPs) and endocrine disrupting chemicals (EDCs). In order to understand the distribution of the contaminants in the environment. We reviewed the current groundwater standards against the collected contaminants, and screened out the contaminants which require further investigation. By knowing the distribution of the contaminants in the environment. We were able to rearrange Groundwater contaminants candidate list. The concerned emerging contaminants include Pentachlorobenzene, Dicyclohexyl Phthalate (DCHP), Diphenyl phthalate (DPHP), Di-n-hexyl phthalate (DNHP), Di-n-propyl phthalate (DPrP), Di (2-ethylhexyl) adipate (DEHA), Boron, lithium and Tungsten etc. Groundwater investigation of 50 groundwater monitoring wells was conducted based on the use of raw materials and historical environmental monitoring data .The results showed that DEHA (0.025~1.33 mg/L) and Boron (2×10-5~9.64×10-4 mg/L) were more significant than other substances. The concentration of Boron exceeded the foreign control limit of 0.3 mg/L, and may be caused by the operation of industrial activities. It is recommended that monitoring and investigation of groundwater be implemented continuously, and review whether the groundwater standards needs to be amended. This project also aims to investigate the possibility of concerned pesticides in the groundwater. Concerned pesticides include Chlordane, Terbufos, Phorate, Paraquat, Butachlor and so on, totally 26 species. The survey area was divided into rice area and vegetable area. A total of 10 simple wells were set up in this project. Phased sampling test was conducted according to the crop growth period, and the results were compared to the farmers pesticide usage record. The result of the investigation showed that Terbufos, Phorate and Butachlor were more significant than others, while the detection of concentrations were ppb level. This project referred to domestic and foreign research reports and databases to establish physical-chemical and toxicology data for the concerned contaminants. At present, data have been gathered for 163 contaminant candidates. Base on the contaminant candidate list and the results of the historical groundwater investigation. Boron and Di(2-ethylhexyl) phthalate(DEHP) were identified to be the priority controlled contaminants and strategies of controlling and survey planning were purposed by this project. This study recommend the government to continuously focus on the environment of the river basins. In addition, the results if this project provided fundamental information for amending the monitoring standard and regulating standards of groundwater in the future. Aforementioned results and suggestions could be submitted to competent authorities as practical implementation references.

英文關鍵字

Emerging Contaminants, Groundwater quality survey, Groundwater contaminants candidate list